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2100-17-6

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  • factory good quality 4-PENTENAL,pent-4-enal;CAS 2100-17-6 CAS NO.2100-17-6

    Cas No: 2100-17-6

  • USD $ 7.0-8.0 / Metric Ton

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2100-17-6 Usage

Chemical Properties

Colorless liquid; cooked brown and roasted aroma.

Uses

4-Pentenal acts as a reagent used in the screening of the phytochemical, antibacterial and cytotoxic activity of medicinal plant of Tamilnadu.

Safety Profile

Moderately toxic by ingestion, inhalation, and skin contact. When heated to decomposition it emits acrid smoke and irritating fumes.

Check Digit Verification of cas no

The CAS Registry Mumber 2100-17-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,1,0 and 0 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 2100-17:
(6*2)+(5*1)+(4*0)+(3*0)+(2*1)+(1*7)=26
26 % 10 = 6
So 2100-17-6 is a valid CAS Registry Number.
InChI:InChI=1/C5H8O/c1-2-3-4-5-6/h2,5H,1,3-4H2

2100-17-6 Well-known Company Product Price

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  • Alfa Aesar

  • (L13351)  4-Pentenal, 97%   

  • 2100-17-6

  • 1g

  • 520.0CNY

  • Detail
  • Alfa Aesar

  • (L13351)  4-Pentenal, 97%   

  • 2100-17-6

  • 5g

  • 1870.0CNY

  • Detail

2100-17-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name pent-4-enal

1.2 Other means of identification

Product number -
Other names 4-PENTENAL

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2100-17-6 SDS

2100-17-6Relevant articles and documents

-

Crandall,J.K.,Mayer,C.F.

, p. 3049 - 3053 (1970)

-

Total Synthesis of Amphirionin-4

Ogura, Yusuke,Sato, Hikaru,Kuwahara, Shigefumi

, p. 2399 - 2402 (2016)

An expeditious enantioselective total synthesis of amphirionin-4, a remarkably potent promoter of the proliferation of ST-2 cells, has been achieved from (±)-(E)-1,4-hexadien-3-ol by an 8-pot sequence that features the Sharpless kinetic resolution, iodoetherification, and the CBS reduction to install the stereocenters, utilization of four one-pot transformations to streamline the synthetic process, and the Stille coupling reaction at nearly the center of the target molecule to complete the total synthesis.

Direct observation of the molecular structural changes during the claisen rearrangement including the transition state

Iwakura, Izumi,Yabushita, Atushi,Kobayashi, Takayoshi

, p. 374 - 375 (2010)

The detailed processes in the Claisen rearrangement were observed. The process was vibrationally excited in the electronic ground state by a stimulated Raman process using a 5-fs pulse. The Claisen rearrangement was found to follow a three-step pathway. At first, the C4-O bond is weakened to generate a bisallyl-like intermediate. Next, the formation of a weak C 1-C6 bond results in the generation of an aromatic-like intermediate. Finally, C4-O breaking and C1-C6 formation occur simultaneously to generate the product.

Asymmetric synthesis of the main core of kaurane family members triggered by an oxidative polycyclization-pinacol tandem process

Desjardins, Samuel,Maertens, Ga?tan,Canesi, Sylvain

, p. 4928 - 4931 (2014)

Polycyclization processes represent expeditious routes used in both nature and the laboratory to produce complex polycyclic molecules. A new stereoselective oxidative variant of such a polycyclization has been developed in which the cascade is triggered by a phenol dearomatization and is concluded by a pinacol transposition. This unprecedented avenue combines the synthetic power of a polycyclization and a transposition in tandem and enables the rapid formation of the tetracyclic main core of kaurane diterpenes containing several asymmetric and quaternary carbon centers in a single step from a simple phenol derivative.

Towards novel difluorinated sugar mimetics; syntheses and conformational analyses of highly-functionalised difluorinated cyclooctenones

Griffith, Gerry A.,Percy, Jonathan M.,Pintat, Stephane,Smith, Clive A.,Spencer, Neil,Uneyama, Emi

, p. 2701 - 2712 (2005)

Highly-functionalised difluorinated cyclooctenones were synthesised from trifluoroethanol using either metallated difluoroenol acetal or carbamate chemistry, followed by a [2,3]-Wittig rearrangement or aldol reaction. Efficient RCM reactions afforded the title compounds which showed rather restricted fluxional behaviour by VT 19F NMR. Topological characterisation by molecular modelling and NOESY/ROESY experiments offered a number of challenges, but allowed the identification of two favoured boat-chair conformers which interconverted by pseudorotation with relatively large activation barriers. The Royal Society of Chemistry 2005.

Blades

, p. 2269,2270 (1970)

Selective hydroformylation of open-chain conjugated dienes promoted by mesitylene-solvated rhodium atoms to give β,γ unsaturated monoaldehydes

Bertozzi, Sergio,Campigli, Nedo,Vitulli, Giovanni,Lazzaroni, Raffaello,Salvadori, Piero

, p. 41 - 46 (1995)

The hydroformylation of 1,3-butadiene, 2-methyl-1,3-butadiene and 1,3-pentadiene using rhodium vapour-mesitylene cocondesates as a catalytic precursor is reported.The reaction gives β,γ-unsaturated monoaldehydes with high chemoselectivity and regioselectivity. η3-Butenyl complexes, derived from the addition of Rh-H species to the conjugated double-bound system, are likely to be intermediates, as suggested by deuterioformylation experiments. Keywords: Rhodium vapour; Hydroformylation; Conjugated dienes; Catalysis; Unsaturated aldehydes

Gold(I)-catalyzed intramolecular [4+3]-cycloaddition reactions with furan propargyl esters as the substrates: Carbenoid vsstabilized allyl cation

Gung, Benjamin W.,Conyers, Ryan C.,Wonser, Josh

, p. 1238 - 1242 (2013)

The tricyclic ring system with an oxabicyclo[3.2.1]octadiene and a fused six-membered ring was produced efficiently using the readily available propargyl ester furan substrate in the presence of a Au(I) complex. The reaction involves a tandem 3,3-rearrangement of the propargyl ester followed by an intramolecular [4+3]-cycloaddition reaction. Both the primary ligand of the gold complex (N-heterocyclic carbene; NHC) and a neutral dynamic ligand (PhCN) are important for the success of the reaction. Georg Thieme Verlag Stuttgart. New York.

Mok

, p. 1432 (1970)

Photoinduced Palladium-Catalyzed Dicarbofunctionalization of Terminal Alkynes

Yang, Zhen,Koenigs, Rene M.

supporting information, p. 3694 - 3699 (2021/02/01)

Herein, a conceptually distinct approach was developed that allowed for the dicarbofunctionalization of alkynes at room temperature using simple, bench-stable alkyl iodides and a second molecule of alkyne as coupling partner. Specifically, the photochemical activation of palladium complexes enabled this strategic dicarbofunctionalization via addition of alkyl radicals from secondary and tertiary alkyl iodides and formation of an intermediate palladium vinyl complex that could undergo subsequent Sonogashira reaction with a second alkyne molecule. This alkylation–alkynylation sequence allowed the one-step synthesis of 1,3-enynes including heteroarenes and biologically active compounds with high efficiency without exogenous photosensitizers or oxidants and now opens up pathways towards cascade reactions via photochemical palladium catalysis.

A Modular and Diastereoselective 5 + 1 Cyclization Approach to N-(Hetero)Aryl Piperidines

Larsen, Matthew A.,Hennessy, Elisabeth T.,Deem, Madeleine C.,Lam, Yu-Hong,Saurí, Josep,Sather, Aaron C.

supporting information, p. 726 - 732 (2020/01/31)

A new general de novo synthesis of pharmaceutically important N-(hetero)aryl piperidines is reported. This protocol uses a robustly diastereoselective reductive amination/aza-Michael reaction sequence to achieve rapid construction of complex polysubstituted ring systems starting from widely available heterocyclic amine nucleophiles and carbonyl electrophiles. Notably, the diastereoselectivity of this process is enhanced by the presence of water, and DFT calculations support a stereochemical model involving a facially selective protonation of a water-coordinated enol intermediate.

Nickel-Catalyzed Selective Reduction of Carboxylic Acids to Aldehydes

Iosub, Andrei V.,Morav?ík, ?tefan,Wallentin, Carl-Johan,Bergman, Joakim

supporting information, p. 7804 - 7808 (2019/10/14)

The direct reduction of carboxylic acids to aldehydes is a fundamental transformation in organic synthesis. The combination of an air-stable Ni precatalyst, dimethyl dicarbonate as an activator, and silane reductant effects this reduction for a wide variety of substrates, including pharmaceutically relevant structures, in good yields and with no overreduction to alcohols. Moreover, this methodology is scalable, allows access to deuterated aldehydes, and is also compatible with one-pot utilization of the aldehyde products.

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