2100-23-4Relevant articles and documents
Direct Iodination of Aromatic Compounds with Iodine and Alumina-Suppored Copper(II) Chloride or Sulfate
Kodomari, Mitsuo,Amanokura, Natsuki,Takeuchi, Kiyoshi,Yoshitomi, Suehiko
, p. 306 - 308 (1992)
The iodination of aromatic compounds (polymethylbenzenes, alkyl phenyl ethers, and polynuclear aromatic hydrocarbons) with iodine in combination with copper(II) chloride or sulfate supported on alumina proceeds well under mild conditions to selectively gi
Synthesis of polysubstituted iodobenzene derivatives from alkynylsilanes and 1,3-dienes via diels-alder/oxidation/iodination reaction sequence
Mockel, Robert,Hilt, Gerhard
supporting information, p. 1644 - 1647 (2015/04/14)
The cobalt-catalyzed Diels-Alder reaction of trimethylsilyl-substituted alkynes with 1,3-dienes led to dihydroaromatic intermediates which were transformed into iodobenzene derivatives. For this transformation, the dihydroaromatic intermediates had to be oxidized and the trimethylsilyl-substituted arene had to undergo a silicon-iodine exchange reaction. For this purpose, a number of oxidizing agents and iodonium sources were tested in order to realize the desired two transformations in a single step. Eventually, the combination of tert-butyl hydroperoxide (TBHP), zinc iodide, and potassium carbonate led to the desired oxidation/iodination in good to excellent yields in a short reaction time at ambient temperatures.
Simple and regioselective oxyiodination of aromatic compounds with ammonium iodide and Oxone
Krishna Mohan,Narender,Kulkarni
, p. 8015 - 8018 (2007/10/03)
Oxyiodination of aromatic compounds using NH4I and Oxone gives high yields and selectivity. A simple method for the iodination of aromatic compounds using NH4I as the iodine source and Oxone as the oxidant is described.
