2102-12-7

Upstream product

• 1165952-91-9 cyclohexa-1,3-diene 
• 73223-81-1 1,4-cyclohexanediol-d12 
• 1165952-92-0 cyclohexa-1,4-diene 

Relevant academic research and scientific papers

INHIBITORS OF INFLUENZA VIRUSES REPLICATION

Polymorphic forms of Compound (1) or a pharmaceutically acceptable salt thereof, wherein Compound (1) is represented by the following structural formula: are Form A of HCl salt of Compound (1)·1/2Η20, Form F of HCl salt of Compound (1)·3Η2

Hydrogen splittings of bis-bicyclic hydrazine radical cations

1H-NMR spectra of bis-bicyclic hydrazine radical allowed of the proton splitting constants under ～2 G, and assignments to position using deuterium labeling were made for several cases. ENDOR spectra measured the hydrogen spllittings over 2 G. Bridgehead hydrogen splittings constants for sesquibicyclic compounds (bis-N,N'-bicyclics) were observed in the range-0.10 to + 0.14 for six examples containing 2,3-diazabicyclo[2.2.2]octyl rings, -0.14 to -0.04 for two 2,3-diazabicyclo[2.2.2]octenyl compounds, +0.02 to +0.21 for four compounds containing 5,6-diazabicyclo[3.2.2]nonyl and nonenyl rings, and +0.35 to +0.84 for containing 2,3-diazabicyclo[2.2.1]heptyl rings, There is not a simple correlation of these bridgehead splitting contants with the lone pair N, C-Hb dihedral angle. For the nine sesquibicyclic hydrazine radical caions studied, the exo splittings in dimethylene bridges were positive, and the endo splittings were nagative in sign. Examination of the W and non-W exp γhydrogen splittings in systems containing bicyclo[2.2.2]octyl rings allowed estimation of the energy difference between double nitrogen inversion conformations.

Fluorescence Quenching and Photoreactions of 2,3-Diazabicyclooct-2-enes. A Case of Charge Transfer and Hydrogen Atom Transfer

A variety of organic compounds have been found to quench the long-lived fluorescence of 2,3-diazabicyclooct-2-ene (DBO), but photochemical reactions take place only with good hydrogen atom donors and tetrahalomethanes.A hydrogen isotope effect on kq of 1.7-3.0 was observed with 1,3- and 1,4-cyclohexadiene.While both quenchers photoreduced DBO, the 1,3-isomer also dimerized to a mixture characteristic of triplet diene.The results are rationalized in terms of the usual encounter complex and ion pair except that the former can undergo hydrogen transfer or react with 1,3-cyclohexadiene.A second case of photochemically induced electron transfer fragmentation was found in the reaction of 1-phenyl-DBO with bromotrichloromethane.

Reactions of Iron Atoms with Benzene and Cyclohexadienes in Argon Matrices: Iron-Benzene Complexes and Photolytic Dehydrogenation of Cyclohexadiene

Three cyclic C6 hydrocarbons - benzene (C6H6), 1,4-cyclohexadiene, and 1,3-cyclohexadiene (both C6H8) - were codeposited with iron atoms in argon matrices at 12-14 K.When iron atoms were cocondensed with benzene, infrared spectra showed the for

Detailed Mechanism of Thermal Hydrogen Migration in Cyclohexadieneiron Tricarbonyl

The thermal isomerization of (cyclohexadiene-5-exo-h-d7)iron tricarbonyl (8) was examined to obtain detailed information about the general mechanism of 1,5-hydrogen shifts in simple cyclic polyolefin iron tricarbonyl complexes.The isotopically labeled sys