210220-69-2Relevant academic research and scientific papers
Photochemically generated nitrilium phosphane-ylid tungsten complexes and their reactivity towards alkyne and nitrile derivatives
Streubel, Rainer,Wilkens, Hendrik,Jones, Peter G.
, p. 2127 - 2128 (2007/10/03)
The photochemically generated nitrilium phosphane-ylid tungsten complex 2 reacts with different activated alkynes, dimethyl acetylenedicarboxylate (DMAD) (i) and ethyl acetylenecarboxylate (ii), and nitriles, ethyl cyanoformate (ECF) (iii) and 1-piperidin
First synthesis and structures of 2H-1,3,2-diazaphosphole tungsten complexes
Wilkens, Hendrik,Streubel, Rainer
, p. 83 - 92 (2007/10/03)
Thermal decomposition of a 2H-azaphosphirene tungsten complex in the presence of various nitrile derivatives yielded 2H-1,3,2-diazaphosphole tungsten complexes. The overall reaction may be described as a 1,3-dipolar cycloaddition of an in situ generated n
