21056-56-4Relevant academic research and scientific papers
Oxidation by chlorine dioxide of methionine and cysteine derivatives to sulfoxides
Loginova,Rubtsova,Kuchin
experimental part, p. 752 - 754 (2009/05/09)
Methionine and cysteine derivatives were oxidized asymmetrically by chlorine dioxide to sulfinyl derivatives.
Manganese Porphyrin Catalyzed Homogeneous Aqueous Oxidation of Organic Molecules by Magnesium Monoperoxyphthalate (MMPP)
Zheng, Tu-Cai,Richardson, David E.
, p. 837 - 840 (2007/10/02)
Magnesium monoperoxyphthalate (MMPP) oxidizes a variety of organic molecules in neutral homogeneous aqueous solutions at room temperature.A water-soluble porphyrin complex, meso-tetrakis-(4-N-methylpyridyl)porhyrinatomanganese(III) chloride, Mn(III)TMPyP(4) Cl, acts as an efficient catalyst for the epoxidation and hydroxylation of water-soluble hydrocarbons.
A General Procedure for the Selective Oxidation of Sulfides to Sulfoxides by Nitric Acid: Tetrabromoaurate(III) Catalyst in a Biphasic System
Gasparrini, Francesco,Giovannoli, Mario,Misiti, Domenico,Natile, Giovanni,Palmieri, Gianni
, p. 1323 - 1328 (2007/10/02)
Tetrabromoaurate(III) is an efficient catalyst for the oxidation of sulfides to sulfoxides by nitric acid in a biphasic system (nitromethane/water).The system is selective and can be applied to the oxidation of any type of dialkyl and alkyl aryl sulfide and also of diaryl sulfides activated by electron-releasing substituents.The nature of the active species has been investigated in relation to the mechanistic aspects.
