210775-52-3Relevant academic research and scientific papers
Fluorescence-responsive H2PO4- receptor based on macrocyclic boron complex
Kameta, Naohiro,Hiratani, Kazuhisa
, p. 536 - 537 (2007/10/03)
Macrocyclic boron complex showed selective fluorescence response toward H2PO4- via hydrogen-bond network, Lewis acid-base interaction, and inhibition of PET. Copyright
Saccharide-accelerated hydrolysis of boronic acid imines
Hartley, James H.,Phillips, Marcus D.,James, Tony D.
, p. 1228 - 1237 (2007/10/03)
Twenty substituted N-benzylidineaniline derivatives have been synthesised and their kinetic behaviour investigated. The rate of hydrolysis of the boronic acid imines was found to be accelerated by added saccharide. Catalytic activity was only observed below the pKa of the boronic acid. Altering the concentration or type of saccharide revealed a Bronsted-like linear free energy relationship, indicating that intramolecular general acid catalysis was operating. Structure-activity relationship studies demonstrated that the system's electronic demands were independent of the boronic acid moiety.
Saccharide accelerated hydrolysis of boronic acid imines
Hartley, James H.,James, Tony D.
, p. 2597 - 2600 (2007/10/03)
Saccharides accelerate the rate of hydrolysis of imines 1 and 2 at pH 7.77. In contrast, the rate of hydrolysis of imine 3 is unaffected by added saccharides.
