210778-76-0

Upstream product

• 76513-69-4 (2-trimethylethylsilylethoxy)methyl chloride 
• 210774-80-4 (3E,5E,11Z)-(7S,8S)-16-(tert-Butyl-dimethyl-silanyloxy)-1-chloro-8-methoxy-2-(1-methoxy-1-methyl-ethoxy)-3,7,11-trimethyl-13-(2-trimethylsilanyl-ethoxymethoxy)-hexadeca-3,5,11-triene 
• 210774-81-5 (5Z,11E,13E)-(9S,10S)-16-Chloro-9-methoxy-15-(1-methoxy-1-methyl-ethoxy)-6,10,14-trimethyl-4-(2-trimethylsilanyl-ethoxymethoxy)-hexadeca-5,11,13-trien-1-ol 
• 210774-79-1 (5Z,11E,13E)-(9S,10S)-1-(tert-Butyl-dimethyl-silanyloxy)-16-chloro-9-methoxy-15-(1-methoxy-1-methyl-ethoxy)-6,10,14-trimethyl-hexadeca-5,11,13-trien-4-ol 
• 210774-78-0 (5Z,11E,13E)-(4S/4R,9S,10S,14S/14R)-16-chloro-4-hydroxy-9-methoxy-15-(2-methoxypropan-2-yloxy)-6,10,14-trimethylhexadeca-5,11,13-trien-1-ol 
• 3112-85-4 methylphenylsulfonate 
• 210774-82-6 (5Z,11E,13E)-(9S,10S)-16-Chloro-9-methoxy-15-(1-methoxy-1-methyl-ethoxy)-6,10,14-trimethyl-4-(2-trimethylsilanyl-ethoxymethoxy)-hexadeca-5,11,13-trienal 

Downstream Products

• 210774-84-8 (5E,7E,13Z)-(9S,10S)-2-Benzenesulfonyl-10-methoxy-5,9,13-trimethyl-15-(2-trimethylsilanyl-ethoxymethoxy)-cycloheptadeca-5,7,13-triene-1,4-dione 
• 210774-83-7 (3E,5E,11Z)-(7S,8S)-17-Benzenesulfonyl-1-chloro-8-methoxy-3,7,11-trimethyl-13-(2-trimethylsilanyl-ethoxymethoxy)-heptadeca-3,5,11-triene-2,16-dione 

Relevant academic research and scientific papers

Synthesis of 17-membered ring macrocycle: studies toward the enantioselective synthesis of fusidic acid

The synthesis of a 17-membered carbocycle by macrocyclization with a chloroketone is reported.Attempts to produce a tetracyclic intermediate for the synthesis of fusidic acid from the transannular aldol and Diels-Alder reactions on this key macrocyclic tr