211057-82-8

Basic information

• Product Name: trans-PtCl₂(PMe₂Ph)(1-methyl-1,4,5,6-tetrahydropyrimidine)
• CAS NO: 211057-82-8
• Molecular Weight: 502.283
• Mol File: 211057-82-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-PtCl₂(PMe₂Ph)(1-methyl-1,4,5,6-tetrahydropyrimidine)(CAS DataBase Reference)
• NIST Chemistry Reference: trans-PtCl₂(PMe₂Ph)(1-methyl-1,4,5,6-tetrahydropyrimidine)(211057-82-8)
• EPA Substance Registry System: trans-PtCl₂(PMe₂Ph)(1-methyl-1,4,5,6-tetrahydropyrimidine)(211057-82-8)

Safety Data

• Hazardous Substances Data: 211057-82-8(Hazardous Substances Data)

Upstream product

• 59599-36-9 di-μ-chlorobis[chloro(dimethylphenylphosphine)platinum(II)] 
• 2304-03-2 1-methyl-1,4,5,6-tetrahydropyrimidine 

Relevant articles and documents

Synthesis of cis- and trans-dichloro(dimethylphenylphosphine)-(1-methyl-1,4,5,6-tetrahydropyrimidine) platinum(II) and their spectral and structural characterization

Interaction of [{Pt(μ-Cl)Cl(PMe2Ph)}2] with 1-methyl-1,4,5,6-tetrahydropyrimidine, L (R=Me), in boiling toluene produced a mixture of cis- and trans- isomers of [PtCl2(PMe2Ph){N=CH(Me)CH2CH2CH 2}]; trans-complex 2 isomerizes to give thermodynamically more stable corresponding cis-complex 1 in boiling ethanol. Spectroscopic and X-ray diffraction data permit generalizations about cis- and trans- isomeric pairs to be made. In addition, the trans influence of the ligand L is reliably assessed.