211057-85-1

Basic information

• Product Name: Au(1-thiolate-1,2-dicarba-closo-dodecaborate)(SPPh₃)
• CAS NO: 211057-85-1
• Molecular Weight: 666.609
• Mol File: 211057-85-1.mol

Chemical Properties

• CAS DataBase Reference: Au(1-thiolate-1,2-dicarba-closo-dodecaborate)(SPPh₃)(CAS DataBase Reference)
• NIST Chemistry Reference: Au(1-thiolate-1,2-dicarba-closo-dodecaborate)(SPPh₃)(211057-85-1)
• EPA Substance Registry System: Au(1-thiolate-1,2-dicarba-closo-dodecaborate)(SPPh₃)(211057-85-1)

Safety Data

• Hazardous Substances Data: 211057-85-1(Hazardous Substances Data)

Upstream product

• 17526-07-7 1-thiol-1,2-dicarba-closo-dodecaborane 
• 15279-72-8 chloro(triphenylphosphine sulfide)gold(I) 

Relevant articles and documents

Gold(I) complexes with the ligand 1-thiolate-1,2-dicarba-closo-dodecaborate. Crystal structure of [Au2(1-S-1,2-C2B10H11) 2(μ-dppe)]

Neutral and anionic gold(I) mononuclear derivatives with the 1-thiolate-1,2-dicarba-closo-dodecaborate ligand of stoichiometries [Au(1-S-1,2-C2B10H11)L] and [Au(1-S-1,2-C2B10H11)2]- have been synthesised. The complex [Au(1-S-1,2-C2B10H11)(AsPh3)] is a good starting material for the synthesis of the dinuclear gold(I) derivative [Au2(1-S-1,2-C2B10H11) 2(μ-PP)], where PP is a diphosphine. The compound [Au2(1-S-1,2-C2B10H11)(PPh 3)2]BF4 has also been prepared. The structure of the neutral complex [Au2(1-S-1,2-C2B10H11) 2(μ-dppe)] is confirmed by single-crystal X-ray diffraction. There are no short gold-gold interactions.