21120-03-6Relevant articles and documents
α-Haloalkanesulfonyl Bromides in Organic Synthesis. 3. α-Alkylidene Ketones and 1,3-Oxathiole 3,3-Dioxides from Trimethylsilyl Enol Ethers
Block, Eric,Aslam, Mohammad,Iyer, Rajeshwari,Hutchinson, John
, p. 3664 - 3666 (2007/10/02)
α-Alkylidene ketones and 1,3-oxathiole 3,3-dioxides can be conveniently prepared by treatment of trimethylsilyl enol ethers with α-haloalkanesulfonyl bromides followed by an amine base such as 1,5-diazabicyclonon-5-ene (DBN).