2114-32-1

Usage

Common uses

Flavoring agent and fragrance ingredient

Classification

Ester (formed by the reaction of an alcohol and a carboxylic acid)

Found in

Perfumes, colognes, scented household items

Odor

Sweet, fruity with floral undertones

Used in

Consumer goods for adding pleasant scent

Industry

Food industry (baked goods and confectionery items)

Safety

Can be irritating to skin and eyes

Handling

Should be used in accordance with safety guidelines

InChI:InChI=1/C11H20O2/c1-3-11(13-9(2)12)10-7-5-4-6-8-10/h10-11H,3-8H2,1-2H3

Upstream product

• 7014-63-3 1-<1-Acetoxy-allyl>-cyclohexen-(1) 
• 557-20-0 diethylzinc 
• 108-24-7 acetic anhydride 
• 2043-61-0 cyclohexanecarbaldehyde 
• 7014-61-1 1-<1-Acetoxy-propin-(2)-yl>-cyclohexen-(1) 

Relevant academic research and scientific papers

Planar- and central-chiral N,O-[2.2]paracyclophane ligands: Non-linear-like effects and activity

The non-linear-like effect (NLLE), activity, temperature dependence, and kinetics of hydroxy-[2.2]paracyclophane ketimine ligands have been investigated with the 1,2-addition reaction of diethylzinc to cyclohexanecarbaldehyde. A linear correlation between the enantiomeric excess of AHPC ketimine ligands bearing a phenylethyl side group and the product was observed with 0.5 mol% of catalyst loading. On increasing the catalyst loading to 4 mol%, a precipitate of the inactive heterochiral species was formed and resulted in a positive non-linear-like effect. The enantiomeric ratio was found to have linear temperature dependence.

Catalysts for asymmetric addition of organozinc reagents to aldehydes and method for preparation

Novel chiral aminoalcohol catalysts and methods for their preparation are provided. The first catalyst is prepared via selective hydrogenation of one of two benzene rings in a precursor. The aminoalcohol promotes the asymmetric addition of organozinc reagents to aldehydes to afford optically active alcohols or their esters. The second catalyst is prepared by selective dialkylation of 3-exo-aminoisoborneol with a 2-haloethyl ether. The aminoalcohol promotes the addition of organozinc reagents to aliphatic aldehydes containing a β-branch with greatly enhanced enantioselectivity relative to DAIB.