211567-31-6

Basic information

• Product Name: 1-octyl 2-amino-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside
• Synonyms: 1-octyl 2-amino-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside
• CAS NO: 211567-31-6
• Molecular Weight: 379.497
• Mol File: 211567-31-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-octyl 2-amino-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 1-octyl 2-amino-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside(211567-31-6)
• EPA Substance Registry System: 1-octyl 2-amino-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside(211567-31-6)

Safety Data

• Hazardous Substances Data: 211567-31-6(Hazardous Substances Data)

Upstream product

• 3068-34-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester 
• 211567-25-8 Methanesulfonic acid (2R,4aR,6R,7R,8R,8aR)-7-acetylamino-6-octyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 173725-22-9 n-octyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside 
• 147126-58-7 octyl 2-(acetylamino)-2-deoxy-β-D-glucopyranoside 
• 111-87-5 octanol 
• 211567-28-1 N-((2R,4aR,6R,7R,8S,8aS)-8-Hydroxy-6-octyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-acetamide 
• 196876-39-8 1-octyl 2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside 

Downstream Products

• 211567-34-9 Bis-(2-chloro-ethyl)-((3aR,4R,5aR,8R,9aR,9bS)-4-octyloxy-2-oxo-8-phenyl-octahydro-1,5,7,9-tetraoxa-3-aza-2λ⁵-phospha-cyclopenta[a]naphthalen-2-yl)-amine 

Relevant articles and documents

Alkylating agents from sugars. Cyclophosphamides derived from 2-amino- 2-deoxy-D-allose

Cyclophosphamides derived from alkyl 2-amino-4,6-O-benzylidene-2-deoxy- β-D-allopyranosides have been synthesized with good yield by treatment of the corresponding 2-amino-2-deoxy-D-allose derivatives with bis(2- chloroethyl)phosphoramide dichloride. The ring-forming reaction took place with very high diastereoselectivity. Subsequent hydrogenolysis gave excellent yields of cyclophosphamides derived from alkyl 2-amino-2-deoxy-β-D- allopyranosides, with hydrophilicity greater than that of the precursors. The starting material was easily available from 2-acetamido-2-deoxy-D-glucose.