21159-73-9

Upstream product

• 13153-47-4 (+/-)-exo-2-benzonorbornenol 
• 4453-90-1 1,4-dihydro-1,4-methanonaphthalene 
• 90364-56-0 (+/-)-exo-2-benzonorbornenyl acetate 
• 4453-90-1 1,4-dihydro-1,4-methanonaphthalene 
• 13153-47-4 (1S,4S)-1,2,3,4-Tetrahydro-1,4-methano-naphthalen-2-ol 

Downstream Products

• 58742-04-4 endo-2-amino-1,2,3,4-tetrahydro-1,4-methanonaphthalene 
• 2294-87-3 3-(2-propenyl)indene 
• 58742-05-5 endo-N-Methyl-2-aminobenzonorbornene 

Relevant academic research and scientific papers

EVIDENCE FOR ANTI-BOND MIGRATION IN THE PHOTOREARRANGEMENT OF 2-D-EXOBENZONORBORNENYL-2-CHLORIDE

Photolysis of the title compund to exo-2-benzonorbornenyl methyl ether proceeds with scrambling of the deuterium between C1 and C2, indicative of migration of the anti aryl group.

A convenient route to both enantiomers of endo-2-benzonorbornenol via lipase catalysed resolution of the racemic mixture

Resolution of racemic edo-benzonorbornenol (±)-4 was performed using Candida antarctica lipase (Novozym 435) in benzene (50°C/50 hours) with vinyl acetate as the acyl donor to afford (-)-endo-2-benzonorbornenol (-)-6 and their corresponding (+)-endo-2-ben