211750-85-5

Basic information

• Product Name: TiCl2(η(5)-C5H4PPh2)(η(5)-C5H4SiMe3)
• CAS NO: 211750-85-5
• Molecular Weight: 505.335
• Mol File: 211750-85-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: TiCl2(η(5)-C5H4PPh2)(η(5)-C5H4SiMe3)(CAS DataBase Reference)
• NIST Chemistry Reference: TiCl2(η(5)-C5H4PPh2)(η(5)-C5H4SiMe3)(211750-85-5)
• EPA Substance Registry System: TiCl2(η(5)-C5H4PPh2)(η(5)-C5H4SiMe3)(211750-85-5)

Safety Data

• Hazardous Substances Data: 211750-85-5(Hazardous Substances Data)

Upstream product

• 85320-10-1 [(diphenylphosphino)cyclopentadienyl]thallium 

Downstream Products

• 211750-88-8 [(η(5)-C5H4PPh2)(η(5)-C5H4SiMe3)Ti(SPh)2] 
• 211750-93-5 TiCl2(η(5)-C5H4P(S)Ph2)(η(5)-C5H4SiMe3) 
• 216491-68-8 [Ti(SCCC₄H₉)2(C₅H₄Si(CH₃)3)(C₅H₄P(C₆H₅)2)] 

Relevant articles and documents

Synthesis and characterization of oxo- and thiophosphorylcyclopentadienyl Ti(IV) thiolate complexes.

New titanium (IV) complexes containing diphenyloxo- or diphenylthiophosphorylcyclopentadienyl ligands are obtained by reaction of diphenylphosphinocyclopentadienyl derivatives with the appropriate oxidizer (S8 or H2O2). The crystal structures of [(η5-C5H4P(S)Ph2)(η5-C5H4SiMe3)TiCl2] 3 and [(η5-C5H4P(S)Ph2)2Ti( SPh)2]·C4H10O 7 indicate in both cases, a pseudo-tetrahedral arrangement around the titanium atom. The two SPh ligands in compound 7 are orientated in opposite sites of the TiS2 plane, which suggests an anti conformation for this molecule.