21177-77-5Relevant academic research and scientific papers
Solid-phase parallel synthesis of phosphite ligands
Swennenhuis, Bert H. G.,Chen, Ruifang,Van Leeuwen, Piet W. N. M.,De Vries, Johannes G.,Kamer, Paul C. J.
supporting information; experimental part, p. 989 - 992 (2009/05/07)
Various routes for the synthesis of polymer-bound phosphites and phosphoramidites have been investigated. In the presence of a suitable activator the supported phosphoramidites react cleanly with alcohols to give the corresponding monodentate phosphite ligands in solution. We have applied this novel solid-phase route in the parallel synthesis of several monodentate chiral and achiral phosphite ligands.
