211801-79-5

Basic information

• Product Name: 4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside
• Synonyms: 4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside
• CAS NO: 211801-79-5
• Molecular Weight: 454.498
• Mol File: 211801-79-5.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: 4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside(211801-79-5)
• EPA Substance Registry System: 4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside(211801-79-5)

Safety Data

• Hazardous Substances Data: 211801-79-5(Hazardous Substances Data)

Upstream product

• 530-26-7 D-Mannose 
• 108-24-7 acetic anhydride 
• 106-45-6 para-thiocresol 
• 103-19-5 di(p-tolyl) disulfide 
• 4163-65-9 per-O-acetyl-α-D-mannopyranose 
• 83-87-4 D-Mannose pentaacetate 

Downstream Products

• 457931-46-3 4-methylphenyl 1-thio-α-D-mannopyranoside 
• 1407152-08-2 p-tolyl 6-O-benzoyl-2,4-di-O-benzylthio-α-D-mannopyranoside 
• 1407151-91-0 p-tolyl 3-O-(2-O-benzoyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-2,4,6-tri-O-benzylthio-α-D-mannopyranoside 
• 1407151-93-2 p-tolyl 3-O-(2-O-benzoyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-6-O-benzoyl-2,4-di-O-benzylthio-α-D-mannopyranoside 
• 1407151-98-7 4-methylphenyl 2-O-benzoyl-3,4-di-O-benzyl-1-thio-α-D-mannopyranoside 
• 1407151-63-6 C₂₁H₂₆O₆S 
• 1407151-65-8 C₄₂H₄₄O₆S 
• 942043-28-9 4-methylphenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside 
• 1407152-00-4 C₃₄H₃₂O₆S 
• 3879-79-6 (2R,3R,4S,5S,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-methoxytetrahydro-2H-pyran 
• 71526-33-5 methyl 2,3,4,6-tetra-O-benzyl-β-D-mannopyranoside 
• 55094-26-3 methyl 2,3,4-tri-O-benzyl-6-O-(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)-α-D-glucopyranoside 
• 55094-26-3 methyl 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl-(1→6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

Stereoselective Phenylselenoglycosylation of Glycals Bearing a Fused Carbonate Moiety toward the Synthesis of 2-Deoxy-β-galactosides and β-Mannosides

A phenylselenoglycosylation reaction of glycal derivatives mediated by diphenyl diselenide and phenyliodine(III) bis(trifluoroacetate) under mild conditions is described. Stereoselective glycosylation has been achieved by installing fused carbonate on those glycals. 3,4-O-Carbonate galactals and 2,3-O-carbonate 2-hydroxyglucals are converted into corresponding glycosides in good yields with excellent β-selectivity, resulting in 2-phenylseleno-2-deoxy-β-galactosides and 2-phenylseleno-β-mannosides which are good precursors of 2-deoxy-β-galactosides and β-mannosides, respectively.

A Concise Synthesis of Oligosaccharides Derived From Lipoarabinomannan (LAM) with Glycosyl Donors Having a Nonparticipating Group at C2

Mycobacteria infection resulting in tuberculosis (TB) is one of the top ten leading causes of death over the world, and lipoarabinomannan (LAM) has been confirmed to play significant roles in this process. In this study, a convenient synthetic approach ha

Triflic acid-mediated synthesis of thioglycosides

An efficient synthesis of thioglycosides from per-acetates in the presence of triflic acid is described. The developed protocol features high reaction rates and product yields. Some reactive sugar series give high efficiency in the presence of sub-stoichiometric trifluoromethanesulfonic acid (TfOH) in contrast to other known protocols that require multiple equivalents of Lewis acids to reach high conversion rates.