211804-28-3Relevant academic research and scientific papers
Synthesis of methyl α-L-callipeltoside
Smith, Garry R.,Finley IV, John J.,Giuliano, Robert M.
, p. 223 - 227 (1998)
The synthesis of callipeltose, a novel amino sugar with the proposed structure, 4-amino-4,6-dideoxy-2,O-3-C-dimethyl-L-talopyranosyl-3,4- urethane, from L-rhamnose is described. Oxime reduction, carbamate cyclization and selective methylation are key steps. The synthesis supports the assignment of the relative stereochemistry of callipeltose.
