211806-80-3

Upstream product

• 211806-78-9 methyl O-(2-azido-2-deoxy-α-D-glucopyranosyl)-(1-3)-2,4-di-O-benzyl-α-L-rhamnopyranoside 
• 211806-79-0 methyl O-(4,6-di-O-acetyl-2-azido-3-O-chloroacetyl-2-deoxy-α-D-glucopyranosyl)-(1-3)-2,4-di-O-benzyl-α-L-rhamnopyranoside 

Downstream Products

• 211806-85-8 methyl O-[3,4,6-tri-O-benzyl-2-O-(4-methoxybenzyl)-α-D-(1-13C)-galactopyranosyl]-(1-3)-O-(4,6-di-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1-3)-2,4-di-O-benzyl-α-L-rhamnopyranoside 
• 211806-89-2 methyl O-(3,4,6-tri-O-benzyl-α-D-(1-13C)-galactopyranosyl)-(1-3)-O-(4,6-di-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1-3)-2,4-di-O-benzyl-α-L-rhamnopyranoside 

Relevant academic research and scientific papers

Measurement of interglycosidic 3J(CH) coupling constants of selectively 13C labeled oligosaccharides by 2D J-resolved 1H NMR spectroscopy

Tri-, tetra-, and penta-saccharide fragments of the O-specific polysaccharide of Shigella dysenteriae type 1 have been prepared in which a D-galactose residue of each oligosaccharide methyl glycoside derivative contains a 13C label at C-1. The interglycosidic coupling constants (3J(CH)) of these 13C nuclei with the H-3 nuclei of the adjacent 2- acetamido-2-deoxy-D-glucose residues have been measured by two-dimensional, J-resolved 1H NMR spectroscopy. The magnitudes of these coupling constants indicate that the trisaccharide is conformationally different to the higher oligosaccharide homologs, in agreement with previous studies of 13C chemical shifts and 1J(CH) values.