211817-42-4

Basic information

• Product Name: (C₆F₅)3GeCu(P(C₆H₅)3)2
• CAS NO: 211817-42-4
• Molecular Weight: 1161.89
• Mol File: 211817-42-4.mol

Chemical Properties

• CAS DataBase Reference: (C₆F₅)3GeCu(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆F₅)3GeCu(P(C₆H₅)3)2(211817-42-4)
• EPA Substance Registry System: (C₆F₅)3GeCu(P(C₆H₅)3)2(211817-42-4)

Safety Data

• Hazardous Substances Data: 211817-42-4(Hazardous Substances Data)

Upstream product

• 42371-50-6 tris(pentafuorophenyl)germane 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Synthesis of germylcopper compounds by hydride method. Crystal structure of (C6F5)3GeCu(PPh3)2

Germylcopper compounds Ph3GeCu(PPh3)3 (1) and (C6F5)3GeCu(PPh3)2 (2) were synthesized by reaction of organogermanium hydrides R3GeH (R=Ph, C6F5) with t-BuOCu in the presence of PPh3. The crystal structure of 2 and its analogous {(C6F5)3GeCu(PPh3)2}(THF) 2 (3) with two additional solvate THF molecules have been determined by X-ray diffraction method. In both 2 and 3 crystals the Cu atom is bonded to the Ge atom of (C6F5)3Ge group and the two P atoms of PPh3 ligands and have a slightly distorted planar-trigonal environments. The Cu-Ge distances are 2.370(2), 2.382(2) A in 2 (for two independent molecules) and 2.348(1) A in 3.