21200-38-4Relevant academic research and scientific papers
A New Synthesis of Substituted Dienes by Reductive Elimination of Allylic Nitro Derivatives
Barlaam, Bernard,Boivin, Jean,Zard, Samir Z.
, p. 1023 - 1026 (1993)
Tertiary allylic nitro compounds, bearing an acetate or a mesylate in β position smoothly undergo a reductive elimination to give conjugated 1,3-dienes when treated with chromous acetate/ 2,2'-dipyridyl in DMF at 110-120 deg C. Key-words: Allylic nitro co
INTERACTIONS DES COMPLEXES DU CHROME OU DU TUNGSTENE A LIGANDE GERMYLENE AVEC DES DIPOLES 1,3(NITRONES, OXAZIRIDINES)
Castel, A.,Riviera, P.,Satge, J.,Ahbala, M.,Jaud, J.
, p. 205 - 218 (1986)
Transition metal-germylene complexes of the type X2GeM(CO)5xTHF (M = Cr, W; X = F, Cl) react with nitrones by nucleophilic exchange at germanium to form new stable adducts.The structure of such a compounds was determined by single crystal X-ray diffraction, and its bonding is discussed in terms of the resulting structural parameters.However, reactions with oxaziridines produce unstable adducts, the decomposition products of which depend on the nature of the oxaziridine.A reaction mechanism is proposed.
Reduction electrochimique de γ-nitrocetones. Conditions experimentales d'acces a des derives de la pyrroline et de la pirrolidine
Cariou, Michel,Hazard, Roland,Jubault, Michel,Tallec, Andre
, p. 2359 - 2366 (2007/10/02)
Optimal conditions for electrosynthesis, at a mercury cathode in hydroalcoholic media, of three classes of nitrogen heterocyclic compounds are set up from an exhaustive study of the electrochemical behaviour of γ-nitroketones 1 and their reduction product
Preparation de pyrrolines N-oxydes, pyrrolines et pyrrolidines par reduction electrochimique de γ-nitrocetones
Cariou,Hazard,Jubault,Tallec
, p. 3961 - 3964 (2007/10/02)
Judiciously selected conditions of controlled potential electrolysis, at a mercury cathode in aqueous organic media, of γ-nitroketones result in quantitative yields of 1-pyrroline 1-oxides, pyrrolines or pyrrolidines.
