21214-62-0

Upstream product

• 1779-49-3 Methyltriphenylphosphonium bromide 
• 5392-40-5 (E/Z)-3,7-dimethyl-2,6-octadienal 
• 19493-09-5 Methylenetriphenylphosphorane 

Downstream Products

• 1361146-69-1 (4R,5S,E)-4-methyl-4-(4-methylpent-3-en-1-yl)-5-phenylpent-2-ene-1,5-diol 
• 1422278-35-0 (1S,2S,3S,4S)-2-methyl-2-(4-methylpent-3-en-1-yl)-3-vinylcyclohexane-1,4-diol 
• 1422278-34-9 (1R,2R,3R,4R)-2-methyl-2-(4-methylpent-3-en-1-yl)-3-vinylcyclohexane-1,4-diol 
• 1422278-46-3 C₃₃H₃₄O₄ 
• 1422278-45-2 C₃₃H₃₄O₄ 
• 1422278-67-8 (1R,2R,3R,4R)-1,3-dimethyl-3-(4-methylpent-3-en-1-yl)-2-vinylcyclohexane-1,4-diol 
• 1422278-66-7 (1S,2S,3S,4S)-1,3-dimethyl-3-(4-methylpent-3-en-1-yl)-2-vinylcyclohexane-1,4-diol 

Relevant academic research and scientific papers

Efficient one-to-one coupling of easily available 1,3-dienes with carbon dioxide

An efficient one-to-one coupling reaction of atmospheric pressure carbon dioxide with 1,3-dienes is realized for the first time through PSiP-pincer type palladium-catalyzed hydrocarboxylation. The reaction is applicable to various 1,3-dienes including easily available chemical feedstock such as 1,3-butadiene and isoprene. This protocol affords a highly useful method for the synthesis of β,γ-unsaturated carboxylic acid derivatives from CO2.

Biosynthesis of C11 and C16 homoterpenes in higher plants; stereo- chemistry of the C-C-bond cleavage reaction

In higher plants the C11 homoterpene 4,8-dimethylnona-1,3,7-triene (1) originates from oxidative degradation of nerolidol (3) or geranylacetone (4). The geometry of the transition state of bond cleavage has been shown to be syn-periplanar, for both 3 and 4 by application of chirally labelled, deuterated precursors to flowers of Magnolia liliiflora nigra or leaves of the Lima bean Phaseolus lunatus. The synthesis of the deuterated, chiral metabolic probes 3 and 8 from nor-farnesene (5), via the enantiomeric epoxides (2S,3R)-6 and ent-6, is described.

(E)-4,8-DIMETHYL-1,3,7-NONATRIENE AND (E,E)-4,8,12-TRIMETHYL-1,3,7,11-TRIDECATETRAENE, TWO UNUSUAL HYDROCARBONS FROM CARDAMOM OIL

The identification of two new natural products, (E)-4,8-dimethyl-1,3,7-nonatriene 1 and (E,E)-4,8,12-trimethyl-1,3,7,11-tridecatetraene 3 is reported.These unusual C11 and C16 hydrocarbons were isolated from essential oil of Elettaria cardamomum Maton var. miniscula Burkhill (Zingiberaceae) and their structures confirmed by synthesis.