212261-68-2Relevant academic research and scientific papers
Metal-free, one-pot synthesis of allylic and benzylic esters via decarboxylation and C-H bond activation
Mo, Hanjie,Chen, Dingben,Xu, Lingzhen,Chen, Di,Pan, Fuyou,Yang, Jianguo
supporting information, p. 209 - 215 (2015/05/05)
A tetrabutylammonium iodide catalyzed method has been developed for the one-pot synthesis of allylic and benzylic esters from α-oxo carboxylic acids and alkenes/alkylbenzenes via decarboxylation and C-H bond activation. Various allylic and benzylic esters were obtained in good yield.
Copper-catalyzed benzylic oxidation of C(sp3)-H bonds
Zhang, Bo,Zhu, Shou-Fei,Zhou, Qi-Lin
supporting information, p. 2033 - 2037 (2013/03/13)
A selective oxidation of benzylic C(sp3)-H bonds to C(sp 3)-O bonds catalyzed by copper complexes of quinoline-imine ligands was developed with peresters as oxidants under mild reaction conditions, which converted benzylic methylenes directly into benzylic alcohols and esters by means of direct C-H bond functionalization.
