212757-45-4Relevant academic research and scientific papers
Asymmetric Total Synthesis of the Complex Polycyclic Xanthone FD-594
Chen, Kuanwei,Gao, Shuanhu,He, Haibing,Xie, Tao,Zheng, Chaoying
supporting information, p. 4360 - 4364 (2020/02/11)
A highly convergent approach was developed to achieve the first asymmetric and scalable total synthesis of FD-594, a complex polycyclic xanthone natural product from Streptomyces sp. TA-0256, in a longest linear sequence (LLS) of 20 steps. The trans-9,10-
Synthesis of both enantiomers of hiburipyranone
Uchida, Kanako,Watanabe, Hidenori,Kitahara, Takeshi
, p. 8975 - 8984 (2007/10/03)
Both enentiomers of hiburipyranone, a cytotoxic metabolite of marine sponge, was synthesized employing Sharpless' asymmetric dihydroxylation as a key step and absolute configuration of the natural compound at C-3 position was determined to be R.
