212915-61-2Relevant articles and documents
Novel and general entry into pseudoguaianolides. Formal and enantioselective synthesis of (+)-confertin
Ohtsuka, Masafumi,Takekawa, Yuki,Shishido, Kozo
, p. 5803 - 5806 (1998)
A novel and general access to pseudoguaianolide sesquiterpenoids has been developed by employing a diastereoselective acyl radical-mediated 7- endo-trigonal mode of cyclization as a key reaction step. The methodology has successfully been applied to the formal enantioselective synthesis of (+)- confertin.