213135-33-2Relevant academic research and scientific papers
Efficient formation of aromatic thiols from thiomethylated precursors
Pinchart, Alain,Dallaire, Carol,Van Bierbeek, Alain,Gingras, Marc
, p. 5479 - 5482 (2007/10/03)
As a model study, a series of linear and branched p-phenylene and m- phenylene sulfides, functionalized by a thiomethyl group, were deprotected to thiols while using various alkyl thiolates at 160°C in DMF. Many complex aromatic thiols were obtained in al
Polysulfurated branched molecules containing functionalized m-phenylene sulfides
Van Bierbeek, Alain,Gingras, Marc
, p. 6283 - 6286 (2007/10/03)
Polysulfurated branched molecules (dendrons) containing functionalized m-phenylene sulfide units were synthesized. An efficient way of making complex aromatic thiols from arylmethylthio groups is shown. A systematic study of the selectivity for producing a new series of phenylene sulfides was achieved. It has lead to the synthesis of rare dendrons containing sulfur and it will open the door to new poly(arylthio) dendrimers.
