213249-71-9Relevant academic research and scientific papers
Higher-order cycloaddition reactions in synthesis. Asymmetric assembly of the C5-C11 segment of the ansa bridge of streptovaricin D
Rigby, James H.,Fales, Kevin R.
, p. 5717 - 5720 (1998)
Auxiliary-controlled, asymmetric Cr(0)-promoted [6π+4π] cycloaddition followed by a ring fragmentation sequence afforded the C5-C11 segment of the ansa bridge found in the ansamycin antibiotics streptovaricin C, D and damavaricin D.
