213314-18-2

Upstream product

• 213314-17-1 2'-diphenylphosphino-2-hydroxy-6-bromo-1,1'-binaphthalene 
• 132548-91-5 (S)-(+)-2-hydroxy-2'-diphenylphosphinoyl-1,1'-binaphthyl 
• 213314-16-0 2'-diphenylphosphinyl-2-hydroxy-6-bromo-1,1'-binaphthalene 

Downstream Products

• 205238-71-7 (R)-2'-diphenylphosphino-6-vibyl-1,1'-binaphthalen-2-yl (S)-1,1'-binaphthalene-2,2'-diyl phosphite 

Relevant academic research and scientific papers

Optically active phosphine derivative having at least two vinyl groups, polymer produced using the same as monomer, and transition metal complexes of these

A 2′-diarylphosphino-1,1′-biphenylen-2-yloxy(6,6′-divinyl-1,1′-binaphthalene-2,2′-diyloxy)phosphine derivative is disclosed, which is represented by general formula (I): wherein Ar is an optionally substituted phenyl or naphthyl; R1and R2

Phosphine derivative and polymer thereof and transition metal complex comprising the same

Disclosed are a phosphine derivative represented by formula (I): wherein Ar represents a substituted or unsubstituted phenyl group or a substituted or unsubstituted naphthyl group, a transition metal complex comprising the phosphine derivative or a polyme

Optically active phosphine derivative having vinyl group, polymer produced using the same as monomer, and transition metal complexes of these

A 6-vinyl-2'-diarylphosphino-1,1'-binaphthalen-2-yloxy(biphenylene-2,2'-diyloxy)phosphine derivative is disclosed, which is represented by general formula (I): wherein Ar is an optionally substituted phenyl or naphthyl; R1 and R2 each independently is a h

Asymmetric hydroformylation of olefins in highly crosslinked polymer matrixes

When polymer-immobilized chiral phosphine-phosphite-Rh(I) complexes were used, the asymmetric hydroformylation of styrene gave 2- and 3- phenylpropanals with a substrate/catalyst ratio of 2000, iso/normal ratios of 84/16 to 89/11, and 89% R enantiomeric excess of 2-phenylpropanal; these results were at the highest level in catalytic activity, regio-, and enantioselectivities. Recovery-reuse of the catalyst was examined. Asymmetric hydroformylation of vinyl acetate, (Z)-2-butene, and 3,3,3-trifluoropropene was also successfully performed with the polymer-supported catalysts.