21336-43-6Relevant articles and documents
Chlorination of Adamantane and Its Derivatives by Carbon Tetrachloride in the Presence of Manganese-, Vanadium-, and Molybdenum-containing Catalysts
Khusnutdinov,Shchadneva,Baiguzina,Lavrent'eva,Burangulova,Dzhemilev
, p. 126 - 133 (2007/10/03)
The feasibility of catalytic chlorination of adamantane and its derivatives by carbon tetrachloride in the presence of manganese-, vanadium-, and molybdenum-containing catalysts activated by nitrile ligands or alcohols was established. The optimum molar ratios of catalyst components and reactants and the optimum reaction conditions for selective syntheses of mono-, di-, and trichlorosubstituted adamantane derivatives with high yields were found.