21344-47-8Relevant academic research and scientific papers
Chemistry of Thienopyridines. XXXV. Mass Spectral Fragmentation Patterns of Some Secondary Amines and Related Imines
Klemm, L. H.,White, D. V.
, p. 1395 - 1396 (2007/10/02)
The mass spectra of some secondary amines and aldimines in the thienopyridine (3) system are presented. α,α-Bis(4-thienopyridylamino)toluene (1) undergoes (a) electron impact-induced dissociation at 80 deg C to give the spectrum of 4-amino-3 (3b) and (b) thermal dissociation at 200 deg C to give a composite spectrum of 3b and its benzylidene derivative.Spectra of benzylamino and dimethylaminobenzylamino derivatives of 3 are dominated by benzyl-type fragments, while benzylideneimino derivatives show more varied fragmentation.
