213547-34-3

Basic information

• Product Name: (S)-2-[(2,4-Dimethoxy-benzyl)-((4E,6E)-6,8-dimethyl-3-oxo-deca-4,6-dienoyl)-amino]-3-phenyl-propionic acid methyl ester
• Synonyms: (S)-2-[(2,4-Dimethoxy-benzyl)-((4E,6E)-6,8-dimethyl-3-oxo-deca-4,6-dienoyl)-amino]-3-phenyl-propionic acid methyl ester
• CAS NO: 213547-34-3
• Molecular Weight: 521.654
• Mol File: 213547-34-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-2-[(2,4-Dimethoxy-benzyl)-((4E,6E)-6,8-dimethyl-3-oxo-deca-4,6-dienoyl)-amino]-3-phenyl-propionic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-[(2,4-Dimethoxy-benzyl)-((4E,6E)-6,8-dimethyl-3-oxo-deca-4,6-dienoyl)-amino]-3-phenyl-propionic acid methyl ester(213547-34-3)
• EPA Substance Registry System: (S)-2-[(2,4-Dimethoxy-benzyl)-((4E,6E)-6,8-dimethyl-3-oxo-deca-4,6-dienoyl)-amino]-3-phenyl-propionic acid methyl ester(213547-34-3)

Safety Data

• Hazardous Substances Data: 213547-34-3(Hazardous Substances Data)

Upstream product

• 213547-32-1 2-(2,4-dimethoxybenzylamino)-3-phenyl-propionic acid methyl ester 
• 213547-31-0 6-((1E,3E)-3,5-Dimethyl-hepta-1,3-dienyl)-2,2-dimethyl-[1,3]dioxin-4-one 
• 613-45-6 2,4-Dimethoxybenzaldehyde 
• 2577-90-4 methyl (2S)-2-amino-3-phenylpropanoate 
• 68799-24-6 (+/-)-2,4-dimethylhex-2-enal 

Downstream Products

• 213547-36-5 (S)-5-Benzyl-1-(2,4-dimethoxy-benzyl)-3-((2E,4E)-4,6-dimethyl-octa-2,4-dienoyl)-4-hydroxy-1,5-dihydro-pyrrol-2-one 

Relevant articles and documents

Synthesis and evaluation of a putative acyl tetramic acid intermediate in tenellin biosynthesis in Beauveria bassiana. A new role for tyrosine

The acyltetramic acid 6 previously proposed as a putative intermediate in tenellin biosynthesis in Beauveria bassiana has been synthesised in two isotopically labelled forms. This compound was not incorporated into tenellin and was not identifiable in extracts of B. bassiana and is unlikely to be involved in tenellin biosynthesis. On the other hand a re-evaluation of the role of tyrosine reveals that it is a good precursor to tenellin and is probably generated in vivo by the action of a phenylalanine hydroxylase directly from L-phenylalanine. Thus the long held contention that acyltetramic acid 6 undergoes oxidative ring expansion to a pyridone no longer appears a valid hypothesis for tenellin biosynthesis.