2135768-85-1

Basic information

• Product Name: 2,7,10,15-tetrabromodibenzo[g,p]chrysene
• CAS NO: 2135768-85-1
• Molecular Weight: 643.997
• Mol File: 2135768-85-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2,7,10,15-tetrabromodibenzo[g,p]chrysene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,7,10,15-tetrabromodibenzo[g,p]chrysene(2135768-85-1)
• EPA Substance Registry System: 2,7,10,15-tetrabromodibenzo[g,p]chrysene(2135768-85-1)

Safety Data

• Hazardous Substances Data: 2135768-85-1(Hazardous Substances Data)

Usage

Chemical compound

2,7,10,15-tetrabromodibenzo[g,p]chrysene
Member of the polycyclic aromatic hydrocarbon (PAH) family
Highly toxic, persistent, and carcinogenic
Classified as a probable human carcinogen by the International Agency for Research on Cancer
Primarily used as a research chemical
Studies related to environmental and human health
Potential impact on air and water pollution
Growing concern about its presence in the environment
Potential impact on human health
Efforts to regulate its use and limit its release into the environment

Upstream product

• 632-51-9 1,1,2,2-tetraphenylethylene 
• 191-68-4 dibenzo[g,p]chrysene 
• 1749-36-6 spiro[9H-fluorene-9,9'(10'H)-phenanthrene]-10'-one 
• 3073-51-6 fluorenopinacol 
• 486-25-9 9-fluorenone 
• 61326-44-1 1,1,2,2-tetrakis(4-bromophenyl)ethene 

Relevant articles and documents

Hetero Cu(III)-Pd(II) Complex of a Dibenzo[g,p]chrysene-Fused Bis-dicarbacorrole with Stable Organic Radical Character

Bis-dicarbacorrole (bis-H3) with two adj-CCNN subunits was synthesized by incorporating a dibenzo[g,p]chrysene moiety into the macrocyclic structure. The two trianionic cores in bis-H3 can stabilize two Cu(III) ions (bis-Cu) or concurrently a Cu(III) cation and a Pd(II) ion in the form of a hetero bis-metal complex (mix-Cu/Pd). As prepared, mix-Cu/Pd displays organic π radical character, as confirmed by various techniques, including electron paramagnetic resonance spectroscopy, cyclic voltammetry, femtosecond transient absorption measurements, and DFT calculations. Radical formation is ascribed to one-electron transfer from the dicarbacorrole backbone to the Pd center allowing the d8 Pd(II) center to be accommodated in a square planner coordination geometry. Nucleus-independent chemical shift and anisotropy of the induced current density calculations provide support for the conclusion that bis-H3 and bis-Cu both display antiaromatic character and contain two formally 16 π-electron dicarbacorrole subunits. On this basis, we suggest that mix-Cu/Pd is best considered as containing a fused 15 π-electron nonaromatic radical subunit and a 16 π-electron antiaromatic subunit. The spectroscopic observations are consistent with these assignments.

Temperature-Dependent Emission and Turn-Off Fluorescence Sensing of Hazardous "quat" Herbicides in Water by a Zn-MOF Based on a Semi-Rigid Dibenzochrysene Tetraacetic Acid Linker

A zinc metal-organic framework, i.e., Zn-MOF (Zn-DBC), with ca. 27% solvent-accessible void volume was synthesized from a rationally designed tetraacid based on sterically insulated dibenzo[g,p]chrysene core; the latter inherently features concave shapes.

Dibenzo [g, p] dibenzo [g, p] decen derivative and a new clean clean sensor derivatives

[Problem] to selectively position the two hydroxyl groups are introduced to clean the sensor 4 [g, p] dibenzo, isomeric products is extremely small, can be made selectively and easily manufacture, and dibenz [g, p] new clean derivative manufactured by the manufacturing method of a sensor. (1) Dibenzo [g, p] [solution] clean sensor brominated, step 4 synthesis of bromide, bromine atoms (2) bromide 4 silylated, silylation process for synthesizing, and, (3) silylation of hydroxy-silyl group by oxidation reaction, synthesis of 2, 7, 10, 15 having a hydroxyl group at step dibenzo [g, p] [g, p] decen tetra- hydroxy dibenzo clean cleaning method for the production of derivatives of the sensor. Also, an oxygen functional group bonded to the dimerization of the fluorenone, 3, 6, 11, 14 and a hydroxyl derivative of [g, p] method for producing clean tetra- hydroxy dibenzo new sensor. [Drawing] no