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1-broMo-2-(2,2-dibroMovinyl)benzene is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 213599-19-0 Structure
  • Basic information

    1. Product Name: 1-broMo-2-(2,2-dibroMovinyl)benzene
    2. Synonyms: 1-broMo-2-(2,2-dibroMovinyl)benzene
    3. CAS NO:213599-19-0
    4. Molecular Formula: C8H5Br3
    5. Molecular Weight: 340.8373
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 213599-19-0.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 315.2±27.0 °C(Predicted)
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: 2.181±0.06 g/cm3(Predicted)
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1-broMo-2-(2,2-dibroMovinyl)benzene(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1-broMo-2-(2,2-dibroMovinyl)benzene(213599-19-0)
    11. EPA Substance Registry System: 1-broMo-2-(2,2-dibroMovinyl)benzene(213599-19-0)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 213599-19-0(Hazardous Substances Data)

213599-19-0 Usage

Derivative of benzene

This compound is derived from benzene, with modifications to its structure, including the attachment of two bromine atoms and a vinyl group.

Vinyl group

1 A vinyl group (C=C) is attached to the benzene ring, which plays a crucial role in the compound's reactivity and its use in organic synthesis.

Organic synthesis reagent

1-Bromo-2-(2,2-dibromovinyl)benzene is commonly used as a reagent in organic synthesis, particularly in the production of pharmaceuticals, agrochemicals, and other fine chemicals.

Building block in synthesis

This compound can be used as a building block in the synthesis of various organic compounds, making it a versatile chemical in the field of organic chemistry.

Reactive nature

Due to the presence of bromine atoms and a vinyl group, 1-Bromo-2-(2,2-dibromovinyl)benzene is a reactive compound and should be handled with care.

Proper storage

To avoid potential hazards, this compound should be stored properly, away from heat, light, and other sources of degradation or reactive conditions.

Check Digit Verification of cas no

The CAS Registry Mumber 213599-19-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,1,3,5,9 and 9 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 213599-19:
(8*2)+(7*1)+(6*3)+(5*5)+(4*9)+(3*9)+(2*1)+(1*9)=140
140 % 10 = 0
So 213599-19-0 is a valid CAS Registry Number.

213599-19-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-bromo-2-(2,2-dibromoethenyl)benzene

1.2 Other means of identification

Product number -
Other names Benzene,1-bromo-2-(2,2-dibromoethenyl)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:213599-19-0 SDS

213599-19-0Relevant articles and documents

Diastereoselective Synthesis of the ABCD Ring System of Rubriflordilactone B

Roth, Hudson G.,Nicewicz, David A.

supporting information, p. 48 - 51 (2021/11/09)

A novel nine-step diastereoselective route to the ABCD ring system of the natural product rubriflordilactone B is reported. Use of an α-substituted butenolide derived from maleic anhydride facilitated a 1,4-conjugate addition to provide a diene. The order in which a ringclosing metathesis and enolate oxidation were performed on this compound dictated the relative stereochemistry of the target. The final product exhibited anisotropic effects during roomerature NMR studies, requiring elevatederature experiments to confirm its identity.

Copper-catalyzed (4+1) and (3+2) cyclizations of iodonium ylides with alkynes

Liang, Hao,He, Xiaobo,Zhang, Yaqi,Chen, Bin,Ouyang, Jia-Sheng,Li, Yongsu,Pan, Bendu,Subba Reddy, Chitreddy V.,Chan, Wesley Ting Kwok,Qiu, Liqin

, p. 11429 - 11432 (2020/10/12)

The copper(ii)-catalyzed (4+1) cyclizations and copper(i)-catalyzed (3+2) cycloadditions of iodonium ylides and alkynes were successfully developed by employing efficient and safe iodonium ylides instead of traditional diazo compounds. Highly functionaliz

Cs2CO3-Mediated Vicinal Thiosulfonylation of 1,1-Dibromo-1-Alkenes with Thiosulfonates: An Expedient Synthesis of (E)-1,2-Thiosulfonylethenes

Reddy, Raju Jannapu,Kumari, Arram Haritha,Kumar, Jangam Jagadesh,Nanubolu, Jagadeesh Babu

supporting information, p. 1587 - 1591 (2019/02/16)

A new and highly efficient vicinal thiosulfonylation of 1,1-dibromo-1-alkenes with thiosulfonates in the presence of cesium carbonate has been developed. The metal-free diheterofunctionalization is an operationally simple to access a wide range of (E)-1,2-thiosulfonylethenes (α-aryl-β-thioarylvinyl sulfones) in moderate to high yields with high levels of stereoselectivities. Further, scalable reactions have been demonstrated for this transformation, thus illustrating its efficiency and practicality. (Figure presented.).

Construction of Phenanthrenes and Chrysenes from β-Bromovinylarenes via Aryne Diels-Alder Reaction/Aromatization

Singh, Vikram,Verma, Ram Subhawan,Khatana, Anil K.,Tiwari, Bhoopendra

supporting information, p. 14161 - 14167 (2019/10/28)

A highly efficient transition-metal-free general method for the synthesis of polycyclic aromatic hydrocarbons like phenanthrenes and chrysenes (and tetraphene) from β-bromovinylarenes and arynes has been developed. The reactions proceed via an aryne Diels-Alder (ADA) reaction, followed by a facile aromatization. This is the first report on direct construction of chrysenes (and tetraphene) using the ADA approach. Unlike the literature method which is limited to only 9/10-substituted derivatives, this method gives access to a wide variety of functionalized phenanthrenes.

Metal-free synthesis of imidazole by BF3·Et2O promoted denitrogenative transannulation of N-sulfonyl-1,2,3-triazole

Yang, Dongdong,Shan, Lihong,Xu, Ze-Feng,Li, Chuan-Ying

supporting information, p. 1461 - 1464 (2018/03/08)

BF3·Et2O promoted metal-free denitrogenative transannulation of N-sulfonyl-1,2,3-triazole was reported. Rather than transition metals, BF3·Et2O was employed for the first time to promote the formation of α-diazoimines from N-sulfonyl-1,2,3-triazoles in nitriles, leading to the synthesis of various imidazoles. The protocol tolerates a broad range of functional groups and could also be applied to the late-stage modification of bioactive molecules, demonstrating the potential of this protocol in organic synthesis. A plausible mechanism was proposed.

Synthesis of 1,1-Disubstituted Indenes and Dihydronaphthalenes through C-C/C-C Bond-Forming Pd-Catalyzed Autotandem Reactions

Barroso, Raquel,Paraja, Miguel,Cabal, María-Paz,Valdés, Carlos

supporting information, p. 4086 - 4089 (2017/08/14)

A novel synthesis of 1,1-disubstituted 1H-indenes is described involving the Pd-catalyzed cascade reaction between o-bromophenyl-β-bromostyrenes and N-tosylhydrazones in a process comprising the consecutive formation of two Csp3-C bonds on the same carbon atom: the cross-coupling of the N-tosylhydrazone with the alkenyl bromide and the intramolecular Heck reaction on the newly formed double bond. A similar approach has been applied to the preparation of 1,1-disubstituted naphthalenes.

One-pot sequential alkynylation and cycloaddition: Regioselective construction and biological evaluation of novel benzoxazole-triazole derivatives

Srivastava, Ananya,Aggarwal, Leena,Jain, Nidhi

, p. 39 - 48 (2015/01/30)

Individually, benzoxazole and triazole moieties are of significant biological interest owing to their importance in drugs and pharmaceuticals. To assess their combined biological impact when woven into one molecule, we designed a novel, regioselective, multicomponent, one-pot (MCOP) approach for the construction of benzoxazole-linked triazoles. The synthesis has been achieved in two sequential steps involving copper-catalyzed alkynylation of benzoxazole followed by a 1,3-dipolar cycloaddition reaction. By combination of these two bioactive units into one core, a series of new benzoxazole-triazole scaffolds has been synthesized and subjected to in vitro antibacterial and anticancer evaluation. Tests against clinical isolates of Staphylococcus aureus and Escherichia coli showed potent Gram-negative activity for compounds 4{1,1,1}, 4{1,1,4}, and 4{1,2,1}. The cytotoxicity of the synthesized library was determined against three cancer cell lines: HeLa, SKBr3, and Hep G2. Compound 4{2,2,2} showed significant cytotoxicity against all the cell lines. These preliminary bioassay evaluations strongly suggest the promise and scope of these novel molecules as therapeutic agents in medical science.

Copper-catalyzed N-alkynylations of sulfoximines with bromoacetylenes

Chen, Xiao Yun,Wang, Long,Frings, Marcus,Bolm, Carsten

supporting information, p. 3796 - 3799 (2014/08/05)

N-Alkynylated sulfoximines have been obtained by copper-catalyzed cross-coupling reactions starting from NH-sulfoximines and bromoacetylenes in moderate to good yields. The reaction conditions are mild, and the substrate scope is wide.

Gold-catalyzed intermolecular oxidation of o-alkynylbiaryls: An easy and practical access to functionalized fluorenes

Pan, Fei,Liu, Shuang,Shu, Chao,Lin, Rong-Kun,Yu, Yong-Fei,Zhou, Jin-Mei,Ye, Long-Wu

supporting information, p. 10726 - 10729 (2014/10/15)

A novel gold-catalyzed intermolecular oxidation of o-alkynylbiaryls has been developed. A variety of functionalized fluorenes are readily accessed by utilizing this non-diazo approach, thus providing a viable alternative to synthetically useful fluorenes. This journal is the Partner Organisations 2014.

A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation

Dieudonne-Vatran, Antoine,Azoulay, Michel,Florent, Jean-Claude

experimental part, p. 2683 - 2691 (2012/04/23)

An original tribromide derivative based, palladium-catalyzed synthesis of 3-substituted-1(2H)-isoquinolone is described based on a regioselective Suzuki-Miyaura C-C coupling on o-halo-(2,2-dihalovinyl)-benzene followed by a palladium catalyzed amination-carbonylation-cyclization reaction. This sequence efficiently proceeds to build up isoquinolone in fair to good yields over a one-pot 3-bond synthesis reaction. The Royal Society of Chemistry 2012.

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