213599-19-0

Basic information

• Product Name: 1-broMo-2-(2,2-dibroMovinyl)benzene
• Synonyms: 1-broMo-2-(2,2-dibroMovinyl)benzene
• CAS NO: 213599-19-0
• Molecular Formula: C₈H₅Br₃
• Molecular Weight: 340.8373
• Mol File: 213599-19-0.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 315.2±27.0 °C(Predicted)
• Appearance: /
• Density: 2.181±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1-broMo-2-(2,2-dibroMovinyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-broMo-2-(2,2-dibroMovinyl)benzene(213599-19-0)
• EPA Substance Registry System: 1-broMo-2-(2,2-dibroMovinyl)benzene(213599-19-0)

Safety Data

• Hazardous Substances Data: 213599-19-0(Hazardous Substances Data)

Usage

Derivative of benzene

This compound is derived from benzene, with modifications to its structure, including the attachment of two bromine atoms and a vinyl group.

Vinyl group

1 A vinyl group (C=C) is attached to the benzene ring, which plays a crucial role in the compound's reactivity and its use in organic synthesis.

Organic synthesis reagent

1-Bromo-2-(2,2-dibromovinyl)benzene is commonly used as a reagent in organic synthesis, particularly in the production of pharmaceuticals, agrochemicals, and other fine chemicals.

Building block in synthesis

This compound can be used as a building block in the synthesis of various organic compounds, making it a versatile chemical in the field of organic chemistry.

Reactive nature

Due to the presence of bromine atoms and a vinyl group, 1-Bromo-2-(2,2-dibromovinyl)benzene is a reactive compound and should be handled with care.

Proper storage

To avoid potential hazards, this compound should be stored properly, away from heat, light, and other sources of degradation or reactive conditions.

Upstream product

• 558-13-4 carbon tetrabromide 
• 6630-33-7 ortho-bromobenzaldehyde 

Downstream Products

• 1109244-74-7 1-bromo-2-(2-bromo-4-phenyl-buta-1,3-dienyl)benzene 
• 1312922-79-4 1-phenyl-2-(thiophen-3-ylethynyl)-1H-indole 
• 1312922-80-7 1-phenyl-2-(pyridin-3-ylethynyl)-1H-indole 
• 1312922-78-3 2-(dec-1-ynyl)-1-phenyl-1H-indole 
• 1312922-77-2 2-((3-methoxyphenyl)ethynyl)-1-phenyl-1H-indole 
• 1312922-86-3 1-p-tolyl-2-((4-(trifluoromethyl)phenyl)ethynyl)-1H-indole 
• 1312922-75-0 1-phenyl-2-((4-(trifluoromethyl)phenyl)ethynyl)-1H-indole 
• 1312922-82-9 1-(2-methoxyphenyl)-2-(phenylethynyl)-1H-indole 
• 1312922-81-8 2-(phenylethynyl)-1-p-tolyl-1H-indole 
• 1312922-83-0 1-(4-methoxyphenyl)-2-(phenylethynyl)-1H-indole 
• 1312922-85-2 1-(4-nitrophenyl)-2-(phenylethynyl)-1H-indole 
• 1312922-74-9 1-phenyl-2-(phenylethynyl)-1H-indole 
• 1312922-84-1 1-(4-fluorophenyl)-2-(phenylethynyl)-1H-indole 
• 1312922-90-9 1-bromo-2-(phenylbuta-1,3-diyn-1-yl)benzene 

Relevant articles and documents

Diastereoselective Synthesis of the ABCD Ring System of Rubriflordilactone B

A novel nine-step diastereoselective route to the ABCD ring system of the natural product rubriflordilactone B is reported. Use of an α-substituted butenolide derived from maleic anhydride facilitated a 1,4-conjugate addition to provide a diene. The order in which a ringclosing metathesis and enolate oxidation were performed on this compound dictated the relative stereochemistry of the target. The final product exhibited anisotropic effects during roomerature NMR studies, requiring elevatederature experiments to confirm its identity.

Cs2CO3-Mediated Vicinal Thiosulfonylation of 1,1-Dibromo-1-Alkenes with Thiosulfonates: An Expedient Synthesis of (E)-1,2-Thiosulfonylethenes

A new and highly efficient vicinal thiosulfonylation of 1,1-dibromo-1-alkenes with thiosulfonates in the presence of cesium carbonate has been developed. The metal-free diheterofunctionalization is an operationally simple to access a wide range of (E)-1,2-thiosulfonylethenes (α-aryl-β-thioarylvinyl sulfones) in moderate to high yields with high levels of stereoselectivities. Further, scalable reactions have been demonstrated for this transformation, thus illustrating its efficiency and practicality. (Figure presented.).

Metal-free synthesis of imidazole by BF3·Et2O promoted denitrogenative transannulation of N-sulfonyl-1,2,3-triazole

BF3·Et2O promoted metal-free denitrogenative transannulation of N-sulfonyl-1,2,3-triazole was reported. Rather than transition metals, BF3·Et2O was employed for the first time to promote the formation of α-diazoimines from N-sulfonyl-1,2,3-triazoles in nitriles, leading to the synthesis of various imidazoles. The protocol tolerates a broad range of functional groups and could also be applied to the late-stage modification of bioactive molecules, demonstrating the potential of this protocol in organic synthesis. A plausible mechanism was proposed.