213697-67-7

Basic information

• Product Name: 2'-BROMO-N,N-DIMETHYL-[1,1'-BIPHENYL]-2-AMINE
• Synonyms: AKOS BAR-2457;2'-BROMO-N,N-DIMETHYL-[1,1'-BIPHENYL]-2-AMINE;2-(DIMETHYLAMINO)-2'-BROMO-1,1'-BIPHENYL;2-(Dimethylamino)-2'-bromo-1,1'-biphenyl 97%
• CAS NO: 213697-67-7
• Molecular Formula: C₁₄H₁₄BrN
• Molecular Weight: 276.17166
• Mol File: 213697-67-7.mol
• Article Data: 4

Chemical Properties

• Melting Point: 58-64 °C
• Boiling Point: 350.987 °C at 760 mmHg
• Flash Point: 166.072 °C
• Appearance: /
• Density: 1.322 g/cm³
• PKA: 4.70±0.18(Predicted)
• CAS DataBase Reference: 2'-BROMO-N,N-DIMETHYL-[1,1'-BIPHENYL]-2-AMINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2'-BROMO-N,N-DIMETHYL-[1,1'-BIPHENYL]-2-AMINE(213697-67-7)
• EPA Substance Registry System: 2'-BROMO-N,N-DIMETHYL-[1,1'-BIPHENYL]-2-AMINE(213697-67-7)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-36-50/53
• Safety Statements: 26-36-60-61
• RIDADR: UN 3082 9/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 213697-67-7(Hazardous Substances Data)

Usage

General Description

2'-Bromo-N,N-dimethyl-[1,1'-biphenyl]-2-amine is a chemical compound that is classified as an amine. It consists of a biphenyl structure with a bromo and dimethylamino group attached to it. 2'-BROMO-N,N-DIMETHYL-[1,1'-BIPHENYL]-2-AMINE can be used in various chemical reactions and synthesis processes as a reagent or intermediate. It has potential applications in pharmaceuticals, agrochemicals, and materials science. Additionally, it is important to handle this compound with proper caution and follow safety guidelines due to its potentially hazardous properties.

Upstream product

• 50-00-0 formaldehyd 
• 73006-87-8 2'-bromo-N-methyl-[1,1'-biphenyl]-2-amine 
• 698-00-0 2-bromo-N,N-dimethylaniline 
• 583-53-9 2,3-dibromobenzene 
• 583-55-1 1-Bromo-2-iodobenzene 
• 89291-23-6 2-(N,N-dimethylamino)phenylboronic acid 

Downstream Products

• 224311-49-3 2'-(di-tert-butylphosphanyl)-N,N-dimethyl-[1,1'-biphenyl]-2-amine 
• 1326737-76-1 2-dimesitylboryl-2'-(N,N-dimethylamino)biphenyl 

Relevant articles and documents

Aryl radical-induced desulfonylative: Ipso -substitution of diaryliodonium salts: An efficient route to sterically hindered biarylamines

By using vicinal aryl sulfonamide substituted diaryliodonium salts, a cascade of desulfonylation/aryl migration was promoted by triethylamine in the synthesis of sterically hindered biarylamines, which operated via a radical-induced reaction pathway. The products were readily converted into a variety of important synthons. Furthermore, coupling reactions of N-methyl biarylamine and 1,6-dibromopyrene provided a potentially attractive molecule in OLEDs.

Synthesis of novel fused azecine ring systems through application of the tert-amino effect

Novel fused azecine ring systems were synthesized via the microwave-assisted thermal isomerization of terphenyl or biphenyl-pyridazine compounds possessing a vinyl and a tert-amino group, through application of a new extension of the tert-amino effect. Substrates for the ring closure were prepared from ortho-dihalobenzene or pyridazinone by consecutive Suzuki couplings with ortho-sec-amino- and formylphenylboronic acids, followed by Knoevenagel condensation of the aldehydes obtained.