213766-24-6

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 1054740-29-2 (2S,3R)-6-(tert-Butyl-diphenyl-silanyloxy)-hexane-1,2,3-triol 
• 213766-14-4 4-(tert-butyl-dimethyl-silanyloxymethyl)-5-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolane 
• 213766-06-4 3-[(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-propionic acid methyl ester 
• 213766-10-0 3-[(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-propan-1-ol 
• 213766-02-0 3-((4R,5S)-5-Hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propionic acid methyl ester 
• 213765-97-0 (4R,5S)-2,2-Dimethyl-4-hydroxymethyl-5-((E)-methoxycarbonylethenyl)-1,3-dioxolane 

Downstream Products

• 213766-34-8 [3-((2S,4R,5S)-5-Allyloxy-5-methyl-2-phenyl-[1,3]dioxan-4-yl)-propoxy]-tert-butyl-diphenyl-silane 
• 213766-78-0 (2S,4aS,6S,7R,9aR)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4a-methyl-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213766-72-4 2-[(2S,4aS,6S,7R,9aR)-7-(tert-Butyl-dimethyl-silanyloxy)-4a-methyl-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl]-ethanol 
• 213766-83-7 (2S,4aS,6S,9aR)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4a-methyl-2-phenyl-tetrahydro-1,3,5-trioxa-benzocyclohepten-7-one 
• 213766-89-3 (2S,4aS,6R,9aR)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4a-methyl-2-phenyl-tetrahydro-1,3,5-trioxa-benzocyclohepten-7-one 
• 213766-67-7 tert-Butyl-dimethyl-((2S,4aS,6S,7R,9aR)-4a-methyl-2-phenyl-6-vinyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-yloxy)-silane 
• 213766-75-7 (2S,4aS,6S,7R,9aR)-6-(2-Hydroxy-ethyl)-4a-methyl-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213766-54-2 (2S,4aS,6S,7R,9aR)-4a-Methyl-2-phenyl-6-vinyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213766-29-1 (2S,4R,5S)-4-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-5-methyl-2-phenyl-[1,3]dioxan-5-ol 

Relevant academic research and scientific papers

Synthesis of the E ring of gambierol

The synthesis of the E ring of gambierol was achieved from D-ribose via the intramolecular reaction of allylstannane with an aldehyde as a key step. The undesired stereoisomer formed in this reaction was converted to the desired product by using DBU isome