213819-86-4

Upstream product

• 90358-01-3 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl trichloroacetimidate 
• 60538-19-4 N-(tert-butoxycarbonyl)-l-threonine methyl ester 
• 213820-05-4 5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-1,2-N,O-isopropylidene-2-(tert-butoxycarbonylamino)-D-threo-L-gulo-decitol 
• 213820-02-1 5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,4-dideoxy-1,2-N,O-isopropylidene-2-(tert-butoxycarbonylamino)-D-threo-L-gulo-3-deculose 
• 1013028-28-8 (4R)-4-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]-2,2-dimethyl-N-(tert-butoxycarbonyl)-1,3-oxazolidine 
• 213819-91-1 (4R)-2,2-dimethyl-N-(tert-butoxycarbonyl)-4-(1-trimethylsilyloxyvinyl)-1,3-oxazolidine 
• 156173-83-0 (4R)-4-[(R)-1-hydroxyethyl]-2,2-dimethyl-N-(tert-butoxycarbonyl)-1,3-oxazolidine 
• 167102-63-8 (R)-N,O-isopropylidenyl-4-(N-tert-butyloxycarbonylamino)-3-oxo-2-butanone 
• 152491-86-6 tert-butyl ((2R,3R)-3-((tert-butyldimethylsilyl)oxy)-1-hydroxybutan-2-yl)carbamate 
• 142729-69-9 (2S,3R)-methyl 2-((tert-butoxycarbonyl)amino)-3-((tert-butyldimethylsilyl)oxy)butanoate 
• 99216-67-8 2-<<(tert-butoxy)carbonyl>amino>butane-1,3-diol 

Relevant academic research and scientific papers

Design and use of an oxazolidine silyl enol ether as a new homoalanine carbanion equivalent for the synthesis of carbon-linked isosteres of O- glycosyl serine and N-glycosyl asparagine

A trimethylsilyl enol ether carrying the N-Boc 2,2-dimethyloxazolidine ring was designed to serve as a synthetic equivalent of the homoalanine carbanion for the introduction of the α-amino acid side chain at the anomeric carbon of sugars. This new functio

Synthesis of methylene isosteres of α- And β-D-galactopyranosyl-L-serine

The BF3·Et2O promoted coupling of tetra-O-benzyl-α-D-galactopyranosyl trichloroacetimidate with a silyl enol ether carrying an oxazolidine ring leads to the α-C-glycosylmethyl ketone (32%, 95% ds) that is converted into the title α-C