213828-81-0Relevant academic research and scientific papers
Design and use of an oxazolidine silyl enol ether as a new homoalanine carbanion equivalent for the synthesis of carbon-linked isosteres of O- glycosyl serine and N-glycosyl asparagine
Dondoni, Alessandro,Marra, Alberto,Massi, Alessandro
, p. 933 - 944 (2007/10/03)
A trimethylsilyl enol ether carrying the N-Boc 2,2-dimethyloxazolidine ring was designed to serve as a synthetic equivalent of the homoalanine carbanion for the introduction of the α-amino acid side chain at the anomeric carbon of sugars. This new functio
Synthesis of ethylene isosteres of β-D-galactosyl- and β-D-glucosyl- L-asparagine
Dondoni, Alessandro,Massi, Alessandro,Marra, Alberto
, p. 6601 - 6604 (2007/10/03)
The Mukaiyama-type coupling of galactosyl and glucosyl aldehydes with a four-carbon atom silyl enol ether carrying the oxazolidine ring affords the corresponding sugar containing aldols (65-74%) that upon deoxygenation and oxidative cleavage of the hetero
