213829-10-8

Upstream product

• 1663-61-2 triethoxymethylbenzene 
• 617-04-9 (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol 
• 194149-26-3 methyl 2,3:4,6-di-O-benzylidene-α-D-mannopyranoside 

Downstream Products

• 869795-78-8 1,3,6-tri-O-acetyl-2,4-di-O-benzoyl-α-D-mannopyranose 
• 869795-85-7 3,6-di-O-acetyl-2,4-di-O-benzoyl-α-D-mannopyranosyl bromide 
• 869795-79-9 methyl 2,4-di-O-benzoyl-6-O-(3,6-di-O-acetyl-2,4-di-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 869795-80-2 methyl 2,4-di-O-benzoyl-6-O-(2,4-di-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside 

Relevant academic research and scientific papers

Regioselective oxidative cleavage of benzylidene acetals: synthesis of highly functionalized chiral intermediates

A mild and efficient method for the regioselective oxidative cleavage of benzylidene acetals with KBrO3/Na2S2O4 under bi-phasic conditions (EtOAc/H2O), leading to highly functionalized chiral intermed

A short and simple synthesis of branched mannooligosaccharides with [1-13C]-labelled terminal mannose units

Mannosylation with 2,3,4,6-tetra-O-benzoyl-α-D-[1- 13C]mannopyranosyl bromide as a glycosyl donor has been used for the synthesis of 3,6-branched mannotri- and -pentaoside bearing labelled terminal mannopyranose units. Methyl 2,4-di-O-benzoyl-α

An easy access to a 3,6-branched mannopentaoside bearing one terminal [1-13C]-labeled D-mannopyranose residue1

Methyl 2,4-di-O-benzoyl-α-D-mannopyranoside was used as a key intermediate in the synthesis of 3,6-branched mannopentaoside bearing one terminal D-[1-13C]mannopyranose residue, viz., methyl 6-O-[3,6-di-O-(α-D-mannopyranosyl)-α-D-mannopyranosyl)

Regioselective glycosylation of 3,6-unprotected mannoside derivatives: Fast access to high-mannose type oligosaccharides

A regioselective glycosylation of 3,6-unprotected mannoside acceptors was investigated. With glycosyl trichloroacetimidate donors, when an excess of trimethylsilyl trifluoromethanesulfonate is used as the catalyst, 6-O-glycosylation exclusively occurred affording a silylated disaccharide that could be involved in a subsequent glycosylation reaction. As an illustration, the fast synthesis of two trisaccharides and one pentasaccharide was achieved.

Synthesis of a tri- and a tetradeoxy analogue of methyl 3,6-di-O-α-D-mannopyranosyl-α-D-mannopyranoside for investigation of the binding site of various plant lectins

The synthesis of the 2,4,3'-trideoxy and 2,4,3',4'-tetradeoxy analogues of the trimannoside part of the core structure of N-linked glycoproteins, methyl 3,6-di-O-α-D-mannopyranosyl-α-D-mannopyranoside, is described. A 2,4-dideoxy (1→6)-linked disaccharide