21387-86-0Relevant academic research and scientific papers
Easy and safe preparations of (diacetoxyiodo)arenes from iodoarenes, with Urea-Hydrogen Peroxide adduct (UHP) as the oxidant and the fully interpreted 1H- and 13C-NMR spectra of the products
Zielinska, Agnieszka,Skulski, Lech
, p. 190 - 194 (2005)
An easy and safe, though only moderately effective method is presented for preparing (diacetoxyiodo)arenes, ArI(OAc)2, from iodoarenes, ArI, using the commercially available and easily handled urea-hydrogen peroxide adduct (UHP) as the oxidant. The reactions take place in anhydrous AcOH/Ac2O/AcONa (a catalyst) mixtures, at 40°C for 3.5 h to afford the purified ArI(OAc)2 in 37-78% yields. The fully interpreted 1H- and 13C-NMR spectra of the ArI(OAc)2 products are reported.
