213899-37-7

Basic information

• Product Name: 2H-Pyran-2-one,tetrahydro-3-methyl-6-(1-methylethyl)-,(3R,6S)-(9CI)
• Synonyms: 2H-Pyran-2-one,tetrahydro-3-methyl-6-(1-methylethyl)-,(3R,6S)-(9CI)
• CAS NO: 213899-37-7
• Molecular Formula: C9H16O2
• Molecular Weight: 156.22
• Product Categories: ISOPROPYL
• Mol File: 213899-37-7.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2H-Pyran-2-one,tetrahydro-3-methyl-6-(1-methylethyl)-,(3R,6S)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Pyran-2-one,tetrahydro-3-methyl-6-(1-methylethyl)-,(3R,6S)-(9CI)(213899-37-7)
• EPA Substance Registry System: 2H-Pyran-2-one,tetrahydro-3-methyl-6-(1-methylethyl)-,(3R,6S)-(9CI)(213899-37-7)

Safety Data

• Hazardous Substances Data: 213899-37-7(Hazardous Substances Data)

Upstream product

• 78-79-5 isoprene 

Relevant articles and documents

Intramolecular stereoselective protonation of aldehyde-derived enolates

Picking sides: Asymmetric protonation of the titled compounds poses a most significant challenge and has been addressed by taking advantage of internal protonation and subsequent hemiacetal formation to avoid epimerization (see scheme). The substrates employed in these transformations can be easily accessed through a sequence of vinylogous aldol reactions with subsequent conjugate reductions.