213979-93-2Relevant academic research and scientific papers
Direct amination of secondary alcohols using ammonia
Pingen, Dennis,Mueller, Christian,Vogt, Dieter
supporting information; experimental part, p. 8130 - 8133 (2011/02/22)
Hydrogen shuttle: For the first time secondary alcohols and ammonia can be directly converted into primary amines with a selectivity of up to 99% by using a simple ruthenium/phosphine catalyst (see scheme; R1, R2= alkyl, aryl, alkenyl; M=[Ru3(CO)12]; and L=phosphine ligand).
