Welcome to LookChem.com Sign In|Join Free

CAS

  • or

214192-22-0

(((CH3)2PCH2)2)Pt(C6H3F2)(O2CCF3) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

214192-22-0 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 214192-22-0 Structure

  • Basic information

    1. Product Name: (((CH3)2PCH2)2)Pt(C6H3F2)(O2CCF3)
    2. Synonyms:
    3. CAS NO:214192-22-0
    4. Molecular Formula:
    5. Molecular Weight: 571.323
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 214192-22-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (((CH3)2PCH2)2)Pt(C6H3F2)(O2CCF3)(CAS DataBase Reference)
    10. NIST Chemistry Reference: (((CH3)2PCH2)2)Pt(C6H3F2)(O2CCF3)(214192-22-0)
    11. EPA Substance Registry System: (((CH3)2PCH2)2)Pt(C6H3F2)(O2CCF3)(214192-22-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 214192-22-0(Hazardous Substances Data)

214192-22-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 214192-22-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,1,4,1,9 and 2 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 214192-22:
(8*2)+(7*1)+(6*4)+(5*1)+(4*9)+(3*2)+(2*2)+(1*2)=100
100 % 10 = 0
So 214192-22-0 is a valid CAS Registry Number.

214192-22-0Downstream Products

214192-22-0Relevant articles and documents

Activation of aromatic C-H bonds by (dmpe)Pt(Me)X (X = Me, O2CCF3, OTf) systems

Peters, R. Gregory,White, Shannon,Roddick, Dean M.

, p. 4493 - 4499 (2008/10/08)

A series of complexes (dmpe)Pt(X)2 (X = Me, Cl, O2CCF3, OTf) have been prepared and their thermal stabilities examined. In contrast to (dmpe)Pt(Me)(Cl), which is stable up to 150 °C in benzene solution, thermolysis of (dmpe)Pt(Me)(O2CCF3) in benzene at 125 °C results in methane loss and the formation of (dmpe)Pt(Ph)(O2CCF3) as the major product, along with small amounts of the disproportionation products (dmpe)Pt(O2CCF3)2 and (dmpe)Pt(Ph)2 (8-10%). Kinetic studies in C6H6 and C6D6 indicate that the disappearance of (dmpe)Pt(Me)(O2CCF3) is first-order, with an overall kinetic isotope effect of 3.3(2). Methyl/ aryl metathesis rates are not inhibited by added TBA+O2CCF3-. Thermolysis of (dmpe)Pt(Me)2 in benzene at 180 °C for 18 h gave a mixture of unreacted (dmpe)Pt(Me)2 (15%), (dmpe)Pt(Me)(Ph) (51%), and (dmpe)Pt(Ph)2 (34%). Thermolysis of (dmpe)Pt(Me)(O2CCF3) in either 1,2- or 1,4-difluorobenzene at 125 °C afforded 2:1:1 statistical mixtures of (dmpe)Pt(Ar)(O2CCF3), (dmpe)Pt(Ar)2, and (dmpe)Pt(O2CCF3)2 (Ar = 2,3-C6H3F2 or 2,5-C6H3F2, respectively). Thermolysis of (dmpe)Pt(Me)(O2CCF3) in toluene affords a mixture of ortho, meta, and para tolyl products, (dmpe)Pt(C6H4Me)(O2CCF3). The metathesis rate for polar 1,2-difluorobenzene is not significantly different than that observed for the nonpolar aromatic substrates. Surprisingly, the aryl/aryl exchange rates for (dmpe)Pt(Ph)(O2CCF3) in C6D6 and C7D8 are 10-20 times faster than observed methyl/aryl exchange rates. These data may be accommodated by a mechanism involving a rate-limiting addition of aryl C-H bonds directly to a 4-coordinate (dmpe)Pt(II) or a 3-coordinate (η1-dmpe)Pt(II) center.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 214192-22-0