214207-19-9Relevant academic research and scientific papers
Ligand exchange reaction of sulfoxides in organic synthesis: Sulfoxide version of the Julia-Lythgoe olefination
Satoh, Tsuyoshi,Yamada, Noriko,Asano, Tohru
, p. 6935 - 6938 (2007/10/03)
Reaction of β-mesyloxy sulfoxides, derived from alkyl (or arylmethyl) phenyl sulfoxides and aldehydes in two steps, with alkylmetal (n-BuLi, t- BuLi, or EtMgBr) at -78°C gave olefins in good to excellent yields. This reaction offers a sulfoxide version of the Julia-Lythgoe olefination.
Ligand exchange reaction of sulfoxides in organic synthesis: A novel method for synthesizing acetylenes and allenes from carbonyl compounds through sulfoxides having a trifluoromethanesulfonyloxy group on the β-carbon
Satoh, Tsuyoshi,Itoh, Norifumi,Watanabe, Shizue,Koike, Hirofumi,Matsuno, Haruko,Matsuda, Kenji,Yamakawa, Koji
, p. 9327 - 9338 (2007/10/02)
A novel method for synthesizing acetylenes and allenes from carbonyl compounds is described. Ligand exchange reaction of alkenylsulfoxides having a trifluoromethanesulfonyloxy group on the β-carbon, which were derived from α-alkyl β-ketosulfoxides, with n
