21425-79-6Relevant academic research and scientific papers
Substrate specific silver(I)-catalyzed cycloisomerization of diene involving alkyl rearrangements: Syntheses of 1,2,5,6-tetrahydrocuminic acid, p-menth-3-en-7-ol, and p-menth-3-en-7-al
Inagaki, Fuyuhiko,Matsumoto, Mizuki,Hira, Shisen,Mukai, Chisato
, p. 822 - 825 (2017/09/12)
The novel cationic Ag(I)-catalyzed cycloisomerization, which is associated with alkyl rearrangements, from dimethyl 2-allyl-2-prenylmalonate (1) to dimethyl 4-isopropylcyclohex-3-ene-1,1-dicarboxylate (2) has been developed. Derivatization from the dieste
