214270-40-3Relevant academic research and scientific papers
From cycloheptatriene to enantiopure sugars: Synthesis of 2-deoxyhexoses
Johnson, Carl R.,Golebiowski, Adam,Kozak, Janusz
, p. 331 - 335 (2007/10/03)
meso-Diol 3, prepared from cycloheptatriene, was desymmetrized with Pseudomonas cepacia lipase and isopropenyl acetate to provide enantiopure 4. The latter, through a series of stereocontrolled oxidation reactions, followed by ring cleavage by ozonolysis and oxidative cleavage of a terminal diol with periodate, provided of 2-deoxy-d-xylo-hexose (1) and 2-deoxy-d-arabino-hexose (2), which were characterized as the corresponding alditol pentaacetates. Copyright (C) 1998 Elsevier Science Ltd.
