214409-49-1Relevant academic research and scientific papers
Domino thermal radical cycloaromatization of non-conjugated aromatic hexa- and heptaynes: Synthesis of fluoranthene and benzo[a]rubicene skeletons
Miyawaki, Kazuhiro,Kawano, Tomikazu,Ueda, Ikuo
, p. 1447 - 1451 (2000)
Non-conjugated aromatic hexa- and heptaynes underwent domino thermal radical cycloaromatization at 25°C to yield indenol ring-fused fluoranthene and indenol ring-fused benzo[a]rubicene skeletons with helicity. This multicyclization reaction proceeded regi
Multiple cycloaromatization of novel aromatic enediynes bearing a triggering device on the terminal acetylene carbon
Miyawaki, Kazuhiro,Kawano, Tomikazu,Ueda, Ikuo
, p. 6923 - 6926 (2007/10/03)
Aromatic enediynes (1) bearing a triggering device on the terminal acetylene carbon undergo thermal cyclization at 25°C to yield polyphenylenc ring systems (6, 9, 13, and 15(16)) giving radical intermediates, dehydrobenzene monoradical (12) and didehydrob
