214604-82-7

Upstream product

• 392-56-3 Hexafluorobenzene 
• 95-54-5 1,2-diamino-benzene 

Downstream Products

• 1558041-44-3 2-phenyl-1,3-bis(pentafluorophenyl)-1,3,2-benzodiazaborole 
• 1558041-56-7 1-(1′,3′-bis(pentafluorophenyl)-1,3,2-benzodiazaborolyl)-4-(1″,3″-diethyl-1″,3″,2″-benzodiazaborolyl)-benzene 
• 1558041-60-3 2-(1′,3′-bis(pentafluorophenyl)-1,3,2-benzodiazaborolyl)-5-(1″,3″-diethyl-1″,3″,2″-benzodiazaborolyl)-thiophene 
• 1449376-99-1 2-N-[4-(3,6-di-tert-butylcarbazolyl)phenyl]-1,3-bis(pentafluorophenyl)-1,3,2-benzodiazaborole 
• 1449377-00-7 2[2-(3,6-di-tert-butylcarbazolyl)thien-2-yl]-1,3-bis(pentafluorophenyl)-1,3,2-benzodiazaborole 
• 1446747-52-9 C₂₂H₁₂F₁₀N₂OSn 

Relevant academic research and scientific papers

A series of metal complexes with the non-innocent N,N′- bis(pentafluorophenyl)-o-phenylenediamido ligand: Twisted geometry for tuning the electronic structure

A series of homoleptic complexes with non-innocent ligands derived from N,N′-bis(pentafluorophenyl)-o-phenylenediamine (H2 Fpda) are reported. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [Co II(Fsbqdi)2] (3), and [CuII( Fsbqdi)2] (4) were synthesized, where ( Fsbqdi)1- represents a radical anion formed by one-electron oxidation of the doubly deprotonated H2Fpda. The oxidation states of ligands and metals in complexes 1-4 were assigned by single crystal X-ray crystallography performed at low temperatures. Complex 4 is the first CuII complex where both o-phenylenediamine derived ligands are monoanionic radicals. The bulky N-C6F5 substituents force the complexes 1, 3, and 4 to adopt a twisted geometry (intermediate between square-planar and tetrahedral). The electronic structures of the neutral compounds 1-4 and of some of their cationic and/or anionic neighboring redox states were probed using EPR and UV-VIS-NIR spectroelectrochemistry. The twisted geometry of the complexes results in considerable changes in their electronic structures compared to the well known square-planar complexes while the strongly electron withdrawing N-C6F5 groups have a great influence on redox properties. The Royal Society of Chemistry.

1,3,2-benzodiazaboroles with 1,3-pentafluorophenyl and tetrafluoropyridyl substituents as building blocks in luminescent compounds

The reaction of N-4′-trimethylsilylphenyl-3,6-di-tert-butylcarbazole (3) or N-5′-trimethylsilylthien-2′-yl-3,6-di-tert-butylcarbazole (4) with boron tribromide and subsequently with triphenylphosphane afforded the dibromoborylphenylcarbazole-phosphane add

Polymerization catalysts containing electron-withdrawing amide ligands

The present invention describes methods of making a series of amine-containing organic compounds which are used as ligands for group 3-10 and lanthanide metal compounds. The ligands have electron-withdrawing groups bonded to them. The metal compounds, when combined with a cocatalyst, are catalysts for the polymerization of olefins.