214619-43-9

Upstream product

• 59055-70-8 C-((4S,5R,4'R)-2,2,2',2'-Tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-methylamine 
• 501-53-1 benzyl chloroformate 
• 19139-74-3 2,3:4,5-di-O-isopropylidene-D-arabinitol 
• 72551-02-1 2,3:4,5-Di-O-isopropylidene-1-O-methylsulfonyl-D-arabinitol 
• 114743-85-0 methyl 3,4:5,6-di-O-isopropylidene-D-gluconate 
• 321549-65-9 (4S,4'R,5R)-5-(azidomethyl)-2,2,2',2'-tetramethyl-4,4'-bis(1,3-dioxolane) 
• 38145-93-6 (S)-1-((4R,4'R,5R)-2,2,2',2'-tetramethyl-4,4'-bi(1,3-dioxolan)-5-yl)ethane-1,2-diol 
• 13039-93-5 2,2:4,5-di-O-isopropylidene-D-arabinose 
• 3969-59-3 mannitol triacetonide 

Downstream Products

• 1292309-34-2 C₂₄H₃₁NO₈S 
• 1292309-29-5 benzyl ((4R,5S)-2,2-dimethyl-5-((R)-oxiran-2-yl)-1,3-dioxolan-4-ylmethyl)carbamate 
• 1292309-31-9 benzyl ((4R,5R)-5-((R)-1-hydroxy-2-(4-methoxyphenyl)ethyl)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl)carbamate 
• 853092-30-5 (2R,3R,4R)-2-(4-methoxybenzyl)pyrrolidine-3,4-diol 
• 24150-14-9 benzyl (2R,3R,4R)-3,4-dihydroxy-2-(4-methoxybenzyl)-pyrrolidine-1-carboxylate 
• 214619-40-6 Methanesulfonic acid (R)-1-[(4S,5R)-5-(benzyloxycarbonylamino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2-(tert-butyl-dimethyl-silanyloxy)-ethyl ester 
• 214619-44-0 {(4R,5R)-5-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl}-carbamic acid benzyl ester 
• 105990-42-9 (2S,3R,4R)-2-(hydroxymethyl)pyrrolidine-3,4-diol 

Relevant academic research and scientific papers

A facile and stereoselective synthesis of the C-2 epimer of (+)-deacetylanisomycin

A short, simple and efficient synthesis of the C-2 epimer of (+)-deacetylanisomycin starting from d-mannitol, utilizing an epoxide opening with a Grignard reagent and acid catalysed unusual intramolecular 5-endo-tet cyclization as key steps has been repor

Chirospecific synthesis of 1,4-dideoxy-1,4-imino-D-arabinitol and 1,4-dideoxy-1,4-immo-L-xylitol via one-pot cyclisation

The multi-protected compounds 4 and 5 were treated with 20% iodine in methanol to give 1,4-dideoxy-1,4-imino-D-arabinitol 1 and 1,4-dideoxy-1,4-imino-L-xylitol 2 directly. Iodine was an efficient catalyst for deprotection of O-isopropylidene, O-(tert-butyldimethylsilyl), N-(9-phenylfluoren-9-yl) and N-benzyloxycarbonyl groups, resulting in intramolecular cyclisation.