214629-58-0

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 214827-07-3 C₁₁H₁₅BrO₂ 
• 214827-08-4 C₁₁H₁₅BrO₂ 
• 173201-02-0 (+)-(1R,4S,4aR,5S,8aS)-1,4,4a,6,7,8a-hexahydro-5-hydroxy-endo-1,4-methanonaphthalen-8(5H)-one 
• 194796-30-0 (+)-(1R,4S,4aR,5S,8aS)-5-tert-Butyldimethylsilyloxy-1,4,4a,6,7,8-hexahydro-endo-1,4-methanonaphthalen-8(5H)-one 

Relevant academic research and scientific papers

Enantioselective construction and utilization of 2-(cyclohex-2-enyl)phenols

Enantioselective construction of 2-(cyclohex-2-enyl)phenols from chiral equivalents of cyclohex-2-enols has been investigated by employing a concurrent retro-Diels-Alder reaction and Claisen rearrangement protocol. Utilizing the enantiomerically pure product obtained, the first enantiocontrolled synthesis of a phenolic natural sesquiterpene (+)-curcudiol, isolated from the marine sponge Didiscus flavus, has been demonstrated.