214629-61-5

Upstream product

• 214629-54-6 (-)-(1S,4R,4aS,5R,8S,8aR)-8-tert-Butyldimethylsilyloxy-1,4,4a,5,6,8,8a-octahydro-5-hydroxy-endo-1,4-methanonaphthalene 
• 214629-56-8 tert-Butyl-dimethyl-((1R,4S,4aR,5S,8S,8aS)-8-m-tolyloxy-1,4,4a,5,6,7,8,8a-octahydro-1,4-methano-naphthalen-5-yloxy)-silane 

Downstream Products

• 214629-64-8 tert-Butyl-[(1S,2R)-2-(2-methoxy-4-methyl-phenyl)-cyclohex-3-enyloxy]-dimethyl-silane 
• 109028-15-1 (S)-2-(6-hydroxy-6-methylheptan-2-yl)-5-methylphenol 
• 170423-76-4 (S)-5-(2-Hydroxy-4-methyl-phenyl)-hexanoic acid methyl ester 
• 214629-66-0 2,2-Dimethyl-propionic acid (4S,5R)-4-(tert-butyl-dimethyl-silanyloxy)-5-(2-methoxy-4-methyl-phenyl)-hexyl ester 
• 214629-65-9 2,2-Dimethyl-propionic acid (4S,5S)-4-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-5-(2-methoxy-4-methyl-phenyl)-hexyl ester 

Relevant academic research and scientific papers

Enantioselective construction and utilization of 2-(cyclohex-2-enyl)phenols

Enantioselective construction of 2-(cyclohex-2-enyl)phenols from chiral equivalents of cyclohex-2-enols has been investigated by employing a concurrent retro-Diels-Alder reaction and Claisen rearrangement protocol. Utilizing the enantiomerically pure product obtained, the first enantiocontrolled synthesis of a phenolic natural sesquiterpene (+)-curcudiol, isolated from the marine sponge Didiscus flavus, has been demonstrated.