214675-88-4Relevant articles and documents
Synthesis of highly functionalised dendrimers based on polyhedral silsesquioxane cores
Jaffres, Paul-Alain,Morris, Russell E.
, p. 2767 - 2770 (1998)
A number of dendrimers based on polyhedral silsesquioxane cores have been synthesised and characterised. The new molecules are prepared by repetitive hydrosilation/alkenylation reactions, which provide a facile and high yield route to dendrimers with a high density of branch ends per generation. Judicious choice of hydrosilating agent [HSiCl3, H(CH3)SiCl2 or H(CH3)2SiCl] produces dendrimers with varying numbers of chain ends, and alkenylating agents of different lengths produce molecules with different physical properties. The 24-vinyl functionalised dendrimer, 5, has been characterised using single-crystal X-ray diffraction techniques. Copyright 1998 by the Royal Society of Chemistry.
Synthesis and computer modelling of hydroxy-derivatised carbosilane dendrimers based on polyhedral silsesquioxane cores
Zhang, Xinjie,Haxton, Katherine J.,Ropartz, Loic,Cole-Hamilton, David J.,Morris, Russell E.
, p. 3261 - 3268 (2007/10/03)
Divergent synthesis methods have been used to prepare 2nd generation dendrimers based on polyhedral silsesquioxane cores with up to 72 terminal groups at their surface. Repetitive hydrosilation/allylation of vinyl-functionalised polyhedral silsesquioxanes produce chlorosilyl- and allyl-derivatised dendrimers respectively. Hydroboration/oxidation of the allyl-functionalised dendrimers produces alcohol (hydroxy) terminated dendrimers. Energy minimisation and molecular dynamics techniques have been used to model the architectures of the dendrimers. The results show the dendrimers are relatively spherical, globular molecules, with a large proportion of the terminal hydroxy groups located in a shell at the exterior of the dendrimer. As the number of terminal groups on the dendrimers increases the number of the dendrimer branches that back fold towards the core of the dendrimer also increases.
